Solid State Ionics, volume 274, pages 8-11

Influence of the Li–Ge–P–S based solid electrolytes on NCA electrochemical performances in all-solid-state lithium batteries

Jingyun Yin 1
Xiayin Yao 2
Gang Peng 2
Jing Yang 1, 3
Zhen Huang 2
Deng Liu 2
Yicheng Tao 2
1
 
Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, 315201, Ningbo, PR China
2
 
Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, 315201 Ningbo, PR China
Publication typeJournal Article
Publication date2015-06-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor3.2
ISSN01672738
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The effect of solid electrolytes, i.e. Li 10 GeP 2 S 12 and Li 3.25 Ge 0.25 P 0.75 S 4 , on the rate and low temperature performances of LiNi 0.8 Co 0.15 Al 0.05 O 2 (NCA) cathode in all solid state lithium batteries is investigated. The ionic conductivities for the synthesized Li 10 GeP 2 S 12 and Li 3.25 Ge 0.25 P 0.75 S 4 at room temperature (RT) are 8.27 × 10 − 3 and 2.03 × 10 − 3  S cm − 1 , respectively. These solid electrolytes are demonstrated as electrolytes for all solid state lithium batteries containing NCA cathode for the first time. The results show that Li 10 GeP 2 S 12 based battery exhibits superior rate performance (72.3 mAh g − 1 at 1 C, RT), cycling stability (capacity retention of 87.1% after 30 cycles at 0.1 C, RT) and low temperature performance (79.2 mAh g − 1 at 0.1 C and − 10 °C), which can be ascribed to its higher ionic conductivity and lower interfacial resistance between Li 10 GeP 2 S 12 and NCA cathode. It is indicated that all solid state lithium batteries with NCA cathode and Li 10 GeP 2 S 12 solid electrolyte can realize its potential application in high power and low temperature conditions.

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Yin J. et al. Influence of the Li–Ge–P–S based solid electrolytes on NCA electrochemical performances in all-solid-state lithium batteries // Solid State Ionics. 2015. Vol. 274. pp. 8-11.
GOST all authors (up to 50) Copy
Yin J., Yao X., Peng G., Yang J., Huang Z., Liu D., Tao Y., Xu X. Influence of the Li–Ge–P–S based solid electrolytes on NCA electrochemical performances in all-solid-state lithium batteries // Solid State Ionics. 2015. Vol. 274. pp. 8-11.
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RIS Copy
TY - JOUR
DO - 10.1016/j.ssi.2015.02.014
UR - https://doi.org/10.1016/j.ssi.2015.02.014
TI - Influence of the Li–Ge–P–S based solid electrolytes on NCA electrochemical performances in all-solid-state lithium batteries
T2 - Solid State Ionics
AU - Yin, Jingyun
AU - Yao, Xiayin
AU - Peng, Gang
AU - Yang, Jing
AU - Huang, Zhen
AU - Liu, Deng
AU - Tao, Yicheng
AU - Xu, Xiaoxiong
PY - 2015
DA - 2015/06/01 00:00:00
PB - Elsevier
SP - 8-11
VL - 274
SN - 0167-2738
ER -
BibTex
Cite this
BibTex Copy
@article{2015_Yin,
author = {Jingyun Yin and Xiayin Yao and Gang Peng and Jing Yang and Zhen Huang and Deng Liu and Yicheng Tao and Xiaoxiong Xu},
title = {Influence of the Li–Ge–P–S based solid electrolytes on NCA electrochemical performances in all-solid-state lithium batteries},
journal = {Solid State Ionics},
year = {2015},
volume = {274},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.ssi.2015.02.014},
pages = {8--11},
doi = {10.1016/j.ssi.2015.02.014}
}
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