Solid State Ionics, volume 291, pages 1-7
Mechanism of lithium ion diffusion in the hexad substituted Li7La3Zr2O12 solid electrolytes
1
Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People's Republic of China
|
Publication type: Journal Article
Publication date: 2016-08-01
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The Li 6.4 La 3 Zr 1.7 M 0.3 O 12 (M = Mo and Cr) and Li 7 − 2 x La 3 Zr 2 − x W x O 12 ( x = 0.1–0.5) solid lithium-ion conductors were prepared by conventional solid state reaction method. The results indicate that partial substitutions by W and Mo ions can stabilize the garnet-like cubic phase of Li–La–Zr–O at room temperature, while the Cr ions substitution cannot even at a content of 15 mol%. The total conductivity of the Li 7 − 2 x La 3 Zr 2 − x W x O 12 lithium conductor is the highest at x = 0.2 (8.7 × 10 − 5 S/cm), and decreases with the increasing W substituting concentration. The Li 6.4 La 3 Zr 1.7 Mo 0.3 O 12 has a higher total conductivity than that of Li 6.4 La 3 Zr 1.7 W 0.3 O 12 . Different from one apparent peak in the Li 7 La 3 Zr 2 O 12 samples, two prominent relaxation-type internal friction peaks related to the short range diffusion of lithium ions were observed in each W or Mo substituted Li 7 La 3 Zr 2 O 12 compounds. The high-temperature IF peaks locate at about 365.9 K and 358.9 K at 1 Hz, corresponding to an activation energy of 0.49 and 0.51 eV for the W and Mo substituted Li 7 La 3 Zr 2 O 12 compounds, respectively. Considering the crystalline structure, it was suggested that the lithium ionic diffusion between 48g(96h)-24d corresponds to the low-temperature peak and 48g(96h)-48g(96h) to the high-temperature peak.
Top-30
Citations by journals
|
1
2
3
|
|
|
Journal of Alloys and Compounds
3 publications, 21.43%
|
|
|
Solid State Ionics
2 publications, 14.29%
|
|
|
Journal of the Electrochemical Society
1 publication, 7.14%
|
|
|
Ionics
1 publication, 7.14%
|
|
|
Ceramics International
1 publication, 7.14%
|
|
|
Materialia
1 publication, 7.14%
|
|
|
International Journal of Hydrogen Energy
1 publication, 7.14%
|
|
|
Journal of the American Ceramic Society
1 publication, 7.14%
|
|
|
Journal of Rare Earths
1 publication, 7.14%
|
|
|
International Journal of Molecular Sciences
1 publication, 7.14%
|
|
|
Russian Chemical Reviews
1 publication, 7.14%
|
|
|
1
2
3
|
Citations by publishers
|
1
2
3
4
5
6
7
8
9
|
|
|
Elsevier
9 publications, 64.29%
|
|
|
The Electrochemical Society
1 publication, 7.14%
|
|
|
Springer Nature
1 publication, 7.14%
|
|
|
Wiley
1 publication, 7.14%
|
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 7.14%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 7.14%
|
|
|
1
2
3
4
5
6
7
8
9
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","",""],"datasets":[{"label":"Citations number","data":[2,2,3,1,1,1,2,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["14.29","14.29","21.43","7.14","7.14","7.14","14.29","14.29"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Journal of Alloys and Compounds","Solid State Ionics","Journal of the Electrochemical Society","Ionics","Ceramics International","Materialia","International Journal of Hydrogen Energy","Journal of the American Ceramic Society","Journal of Rare Earths","International Journal of Molecular Sciences","Russian Chemical Reviews"],"ids":[4015,12542,5297,12191,15103,11140,8699,24329,12501,14627,23802],"codes":[0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/qSRMPRcU9e305ZndYbSqzvtlXr55B5FcWpS97I4M_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[3,2,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[21.43,14.29,7.14,7.14,7.14,7.14,7.14,7.14,7.14,7.14,7.14],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","The Electrochemical Society","Springer Nature","Wiley","Multidisciplinary Digital Publishing Institute (MDPI)","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[17,6916,8,11,202,9422],"codes":[0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[9,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[64.29,7.14,7.14,7.14,7.14,7.14],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,1,0,0,1,0,1,0],"percentage":["0","7.14","0","0","7.14","0","7.14","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[2,1,3,1,0,1,1,2],"percentage":["14.29","7.14","21.43","7.14","0","7.14","7.14","14.29"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,1,1,0,1,0,1,0],"percentage":["0","7.14","7.14","0","7.14","0","7.14","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[2,1,2,0,0,1,1,2],"percentage":["14.29","7.14","14.29","0","0","7.14","7.14","14.29"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,1,0,0,0,0],"percentage":["0","0","0","7.14","0","0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Gao Y. X. et al. Mechanism of lithium ion diffusion in the hexad substituted Li7La3Zr2O12 solid electrolytes // Solid State Ionics. 2016. Vol. 291. pp. 1-7.
GOST all authors (up to 50)
Copy
Gao Y. X., Wang X., Lu H., Zhang L., Ma L., FANG Q. F. Mechanism of lithium ion diffusion in the hexad substituted Li7La3Zr2O12 solid electrolytes // Solid State Ionics. 2016. Vol. 291. pp. 1-7.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.ssi.2016.04.017
UR - https://doi.org/10.1016/j.ssi.2016.04.017
TI - Mechanism of lithium ion diffusion in the hexad substituted Li7La3Zr2O12 solid electrolytes
T2 - Solid State Ionics
AU - Gao, Y. X.
AU - Wang, Xianping
AU - Lu, H.
AU - Zhang, Lai-Chang
AU - Ma, L.
AU - FANG, Q. F.
PY - 2016
DA - 2016/08/01 00:00:00
PB - Elsevier
SP - 1-7
VL - 291
SN - 0167-2738
ER -
Cite this
BibTex
Copy
@article{2016_Gao,
author = {Y. X. Gao and Xianping Wang and H. Lu and Lai-Chang Zhang and L. Ma and Q. F. FANG},
title = {Mechanism of lithium ion diffusion in the hexad substituted Li7La3Zr2O12 solid electrolytes},
journal = {Solid State Ionics},
year = {2016},
volume = {291},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/j.ssi.2016.04.017},
pages = {1--7},
doi = {10.1016/j.ssi.2016.04.017}
}