Solid State Ionics, volume 295, pages 32-40

Study of the glass-to-crystal transformation of the NASICON-type solid electrolyte Li1 + xAlxGe2 − x(PO4)3

Zhongqing Liu ¹

Sabarinathan Venkatachalam ¹

Holger Kirchhain ¹

Leo van Wüllen ¹

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Institute of Physics, Augsburg University, Universitätsstr. 1, 86159 Augsburg (Germany) |

Publication type: Journal Article

Publication date: 2016-11-01

Elsevier

Journal: Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor: 3.2

ISSN: 01672738

DOI: 10.1016/j.ssi.2016.07.006

Copy DOI

General Chemistry

Condensed Matter Physics

General Materials Science

Abstract

In this study, we present a detailed investigation of the glass to crystal transformation in the Li 1 + x Al x Ge 2 − x P 3 O 12 (LAGP) system. Precursor glasses were synthesized following melt-quench and sol-gel procedures. The glass to crystal transition was studied employing X-ray diffraction and advanced solid state nuclear magnetic resonance (solid state NMR) techniques including 7 Li-, 27 Al-, 31 P NMR, 27 Al{ 7 Li}- and 27 Al{ 31 P}-REDOR-NMR as well as 31 P{ 27 Al}-REAPDOR-NMR. Whereas Al-poor LAGP precursor glasses exhibit a direct glass-to-LAGP crystal transition, without any extended change in the Al content of the LAGP crystals and without the formation of side phases, for glasses richer in Al the crystallization of LAGP is accompanied by the formation of AlPO 4 , which for x = 1.0 is the first crystalline phase to precipitate. For these compositions, the first crystalline LAGP phase precipitating contains an Al content lower than the nominal x-value, however, with annealing, more Al is continuously incorporated into the LAGP structure, accompanied by a decrease in the relative amount of the AlPO 4 phase. After surpassing a threshold temperature – which decreases from T = 900 °C for x = 0.4 to 720 °C for x = 0.8 – at which the LAGP phases reaches its highest Al content, close to the nominal composition, Al is gradually expelled from the LAGP structure, forming LGP and AlPO 4 . The findings enable the formation of virtually phase pure LAGP over an extended compositional range until x = 0.8.

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Liu Z. et al. Study of the glass-to-crystal transformation of the NASICON-type solid electrolyte Li1 + xAlxGe2 − x(PO4)3 // Solid State Ionics. 2016. Vol. 295. pp. 32-40.

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Liu Z., Venkatachalam S., Kirchhain H., van Wüllen L. Study of the glass-to-crystal transformation of the NASICON-type solid electrolyte Li1 + xAlxGe2 − x(PO4)3 // Solid State Ionics. 2016. Vol. 295. pp. 32-40.

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RIS Copy

TY - JOUR

DO - 10.1016/j.ssi.2016.07.006

UR - https://doi.org/10.1016/j.ssi.2016.07.006

TI - Study of the glass-to-crystal transformation of the NASICON-type solid electrolyte Li1 + xAlxGe2 − x(PO4)3

T2 - Solid State Ionics

AU - Liu, Zhongqing

AU - Venkatachalam, Sabarinathan

AU - Kirchhain, Holger

AU - van Wüllen, Leo

PY - 2016

DA - 2016/11/01 00:00:00

PB - Elsevier

SP - 32-40

VL - 295

SN - 0167-2738

ER -

BibTex

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BibTex Copy

@article{2016_Liu,

author = {Zhongqing Liu and Sabarinathan Venkatachalam and Holger Kirchhain and Leo van Wüllen},

title = {Study of the glass-to-crystal transformation of the NASICON-type solid electrolyte Li1 + xAlxGe2 − x(PO4)3},

journal = {Solid State Ionics},

year = {2016},

volume = {295},

publisher = {Elsevier},

month = {nov},

url = {https://doi.org/10.1016/j.ssi.2016.07.006},

pages = {32--40},

doi = {10.1016/j.ssi.2016.07.006}

}

Found error?

Publisher

Elsevier

Journal

Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor

3.2

ISSN

01672738 (Print)