Solid State Ionics, volume 296, pages 18-25

Electrochemical characterization of Li10SnP2S12: An electrolyte or a negative electrode for solid state Li-ion batteries?

Ilyas Tarhouchi ^{1, 2}

Virginie Viallet ^{1, 2}

Philippe Vinatier ²

M. Menetrier ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Laboratoire de Réactivité et de Chimie des Solides, Université de Picardie Jules Verne, CNRS UMR#7314, F-80039 Amiens, France |

RS2E, Réseau Français sur le Stockage Electrochimique de l'Energie, CNRS FR#3459, F-80039 Amiens, France |

Publication type: Journal Article

Publication date: 2016-11-01

Elsevier

Journal: Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor: 3.2

ISSN: 01672738

DOI: 10.1016/j.ssi.2016.08.016

Copy DOI

General Chemistry

Condensed Matter Physics

General Materials Science

Abstract

Li10SnP2S12, the tin analogue of the Li10GeP2S12 superionic conductor is characterized. Rietveld refinement of capillary powder XRD confirms that the material provided by NEI Corp. is mainly composed of Li10SnP2S12 with LGPS structure, with some Li2SnS3 impurity. Very strong reactivity at low voltage and vs. Li metal is shown by impedance measurements using Au and Li electrodes, as well as 3-electrode cyclic voltammetry. Galvanostatic measurements in half-cells with liquid and solid electrolytes confirm that Li10SnP2S12 reacts with respectively 16 and 8 lithium per mole of tin below 0.5 V vs. Li+/Li, most probably following a conversion/alloying reaction. Making use of this reactivity, we tested the concept of a LiCoO2/Li10SnP2S12 cell, were the electrolyte also acts as negative electrode at the contact with the negative current collector. 0.5 Li can be deintercalated from such cells, with very poor reversibility as probably hampered by the conversion/alloying reaction in the solid state, at least with a non-optimized electrode formulation. Although the voltage slowly but strongly relaxes when opening the circuit suggesting propagation of the reaction from the negative electrode to the electrolyte, it does not seem to reach the positive since no short-circuit was observed.

By date By citations

Top-30

Citations by journals

	1 2 3
Advanced Energy Materials	Advanced Energy Materials, 3, 9.38% Advanced Energy Materials 3 publications, 9.38%
ACS applied materials & interfaces	ACS applied materials & interfaces, 3, 9.38% ACS applied materials & interfaces 3 publications, 9.38%
Chemistry of Materials	Chemistry of Materials, 2, 6.25% Chemistry of Materials 2 publications, 6.25%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 2, 6.25% Journal of Physical Chemistry C 2 publications, 6.25%
Journal of Power Sources	Journal of Power Sources, 2, 6.25% Journal of Power Sources 2 publications, 6.25%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 2, 6.25% Journal of Materials Chemistry A 2 publications, 6.25%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 1, 3.13% Journal of the Electrochemical Society 1 publication, 3.13%
Nature Materials	Nature Materials, 1, 3.13% Nature Materials 1 publication, 3.13%
Nature Reviews Materials	Nature Reviews Materials, 1, 3.13% Nature Reviews Materials 1 publication, 3.13%
Ceramics International	Ceramics International, 1, 3.13% Ceramics International 1 publication, 3.13%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 1, 3.13% Journal of Alloys and Compounds 1 publication, 3.13%
Solid State Ionics	Solid State Ionics, 1, 3.13% Solid State Ionics 1 publication, 3.13%
Energy Storage Materials	Energy Storage Materials, 1, 3.13% Energy Storage Materials 1 publication, 3.13%
Electrochimica Acta	Electrochimica Acta, 1, 3.13% Electrochimica Acta 1 publication, 3.13%
Physica B: Condensed Matter	Physica B: Condensed Matter, 1, 3.13% Physica B: Condensed Matter 1 publication, 3.13%
Zeitschrift fur Anorganische und Allgemeine Chemie	Zeitschrift fur Anorganische und Allgemeine Chemie, 1, 3.13% Zeitschrift fur Anorganische und Allgemeine Chemie 1 publication, 3.13%
Advanced Materials	Advanced Materials, 1, 3.13% Advanced Materials 1 publication, 3.13%
Chemical Engineering Journal	Chemical Engineering Journal, 1, 3.13% Chemical Engineering Journal 1 publication, 3.13%
ACS Sustainable Chemistry and Engineering	ACS Sustainable Chemistry and Engineering, 1, 3.13% ACS Sustainable Chemistry and Engineering 1 publication, 3.13%
Accounts of Chemical Research	Accounts of Chemical Research, 1, 3.13% Accounts of Chemical Research 1 publication, 3.13%
Energy and Environmental Science	Energy and Environmental Science, 1, 3.13% Energy and Environmental Science 1 publication, 3.13%
Open Engineering	Open Engineering, 1, 3.13% Open Engineering 1 publication, 3.13%
Small	Small, 1, 3.13% Small 1 publication, 3.13%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 3.13% Russian Chemical Reviews 1 publication, 3.13%
	1 2 3

Citations by publishers

	1 2 3 4 5 6 7 8 9
American Chemical Society (ACS)	American Chemical Society (ACS), 9, 28.13% American Chemical Society (ACS) 9 publications, 28.13%
Elsevier	Elsevier, 9, 28.13% Elsevier 9 publications, 28.13%
Wiley	Wiley, 6, 18.75% Wiley 6 publications, 18.75%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 3, 9.38% Royal Society of Chemistry (RSC) 3 publications, 9.38%
Springer Nature	Springer Nature, 2, 6.25% Springer Nature 2 publications, 6.25%
The Electrochemical Society	The Electrochemical Society, 1, 3.13% The Electrochemical Society 1 publication, 3.13%
Walter de Gruyter	Walter de Gruyter, 1, 3.13% Walter de Gruyter 1 publication, 3.13%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 3.13% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 3.13%
	1 2 3 4 5 6 7 8 9

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","",""],"datasets":[{"label":"Citations number","data":[4,9,3,4,5,2,4,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["12.5","28.13","9.38","12.5","15.63","6.25","12.5","3.13"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Advanced Energy Materials","ACS applied materials & interfaces","Chemistry of Materials","Journal of Physical Chemistry C","Journal of Power Sources","Journal of Materials Chemistry A","Journal of the Electrochemical Society","Nature Materials","Nature Reviews Materials","Ceramics International","Journal of Alloys and Compounds","Solid State Ionics","Energy Storage Materials","Electrochimica Acta","Physica B: Condensed Matter","Zeitschrift fur Anorganische und Allgemeine Chemie","Advanced Materials","Chemical Engineering Journal","ACS Sustainable Chemistry and Engineering","Accounts of Chemical Research","Energy and Environmental Science","Open Engineering","Small","Russian Chemical Reviews"],"ids":[22475,1458,6428,8859,14844,14919,5297,12650,8510,15103,4015,12542,3858,15613,18171,18677,25159,16275,18886,1526,10138,17973,9872,23802],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[3,3,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[9.38,9.38,6.25,6.25,6.25,6.25,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Elsevier","Wiley","Royal Society of Chemistry (RSC)","Springer Nature","The Electrochemical Society","Walter de Gruyter","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[40,17,11,123,8,6916,4,9422],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[9,9,6,3,2,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[28.13,28.13,18.75,9.38,6.25,3.13,3.13,3.13],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,1,0,0],"percentage":["0","0","0","0","0","3.13","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,1,0,0,0,0,0,0],"percentage":["0","3.13","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,1,0,0,0,0,0,0],"percentage":["3.13","3.13","0","0","0","0","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[3,7,3,4,5,1,4,1],"percentage":["9.38","21.88","9.38","12.5","15.63","3.13","12.5","3.13"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,1,0,0,0,0,0,0],"percentage":["0","3.13","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[2,3,0,0,1,0,0,0],"percentage":["6.25","9.38","0","0","3.13","0","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[2,5,3,4,4,1,4,1],"percentage":["6.25","15.63","9.38","12.5","12.5","3.13","12.5","3.13"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,0,0,1,0,0],"percentage":["0","0","0","0","0","3.13","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Tarhouchi I. et al. Electrochemical characterization of Li10SnP2S12: An electrolyte or a negative electrode for solid state Li-ion batteries? // Solid State Ionics. 2016. Vol. 296. pp. 18-25.

GOST all authors (up to 50) Copy

Tarhouchi I., Viallet V., Vinatier P., Menetrier M. Electrochemical characterization of Li10SnP2S12: An electrolyte or a negative electrode for solid state Li-ion batteries? // Solid State Ionics. 2016. Vol. 296. pp. 18-25.

RIS |

Cite this