Solid State Ionics, volume 300, pages 38-45
Electrical, mechanical and chemical behavior of Li1.2Zr1.9Sr0.1(PO4)3
Sheila R Smith
1
,
Travis Thompson
1
,
Jeff Sakamoto
1
,
Jan Allen
2
,
D R Baker
2
,
Jeff Wolfenstine
2
1
2
Army Research Laboratory, RDRL-SED-C, 2800 Powder Mill Road, Adelphi, MD 20783 (United States)
|
Publication type: Journal Article
Publication date: 2017-02-01
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The elastic modulus, fracture toughness, ionic conductivity, Li and water stability of dense (~ 97%) fine-grain (~ 10 μm) Li 1.2 Zr 1.9 Sr 0.1 (PO 4 ) 3 (LZSP) consolidated by reactive hot-pressing was investigated. Low values of elastic modulus (25.2 and 40.9 GPa), fracture toughness (0.29 and 0.37 MPa-m 1/2 ), total conductivity (2.1 × 10 − 5 S/cm) at room temperature were exhibited as a result of the presence of microcracks formed during cooling from the hot-pressing temperature. The lattice conductivity of LZSP is 0.85 × 10 − 4 S/cm with an activation energy for bulk conductivity of 0.29 eV. The results of Li/LZSP/Li cell impedance as a function of time and surface examination suggest that LZSP is not stable against metallic lithium. The results of the water stability test suggest that LZSP is a possible membrane for use in aqueous Li-Air cells. The results of this study reveal for the case of lithium zirconium phosphates are as follows: 1] a small grain size is required to prevent microcracking to avoid a reduction in total conductivity and mechanical properties and 2] even though they do not contain a transition metal cation they are not stable against Li at room temperature.
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Citations by publishers
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1 publication, 3.03%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Smith S. R. et al. Electrical, mechanical and chemical behavior of Li1.2Zr1.9Sr0.1(PO4)3 // Solid State Ionics. 2017. Vol. 300. pp. 38-45.
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Smith S. R., Thompson T., Sakamoto J., Allen J., Baker D. R., Wolfenstine J. Electrical, mechanical and chemical behavior of Li1.2Zr1.9Sr0.1(PO4)3 // Solid State Ionics. 2017. Vol. 300. pp. 38-45.
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TY - JOUR
DO - 10.1016/j.ssi.2016.11.032
UR - https://doi.org/10.1016/j.ssi.2016.11.032
TI - Electrical, mechanical and chemical behavior of Li1.2Zr1.9Sr0.1(PO4)3
T2 - Solid State Ionics
AU - Smith, Sheila R
AU - Thompson, Travis
AU - Sakamoto, Jeff
AU - Allen, Jan
AU - Baker, D R
AU - Wolfenstine, Jeff
PY - 2017
DA - 2017/02/01 00:00:00
PB - Elsevier
SP - 38-45
VL - 300
SN - 0167-2738
ER -
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@article{2017_Smith,
author = {Sheila R Smith and Travis Thompson and Jeff Sakamoto and Jan Allen and D R Baker and Jeff Wolfenstine},
title = {Electrical, mechanical and chemical behavior of Li1.2Zr1.9Sr0.1(PO4)3},
journal = {Solid State Ionics},
year = {2017},
volume = {300},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.ssi.2016.11.032},
pages = {38--45},
doi = {10.1016/j.ssi.2016.11.032}
}