Solid State Ionics, volume 300, pages 73-77
Investigation of Mg2+, Sc3+ and Zn2+ doping effects on densification and ionic conductivity of low-temperature sintered Li7La3Zr2O12 garnets
Publication type: Journal Article
Publication date: 2017-02-01
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
Garnet-type solid electrolytes Li 7 La 3 Zr 2 − x Mg 2 x O 12 , Li 7 La 3 Zr 2 − 0.75 x Sc x O 12 and Li 7 − 2 x Zn x La 3 Zr 2 O 12 with x = 0, 0.025, 0.05 and 0.1 were synthesized at 1075 °C by using the traditional solid-state reaction method. It is found that substitution of Mg 2 + and Sc 3 + for Zr 4 + is more effective in improving the Li 7 La 3 Zr 2 O 12 (LLZ)'s densification and ionic conductivity than the substitution of Zn 2 + for Li + . As a result, the highest room-temperature total conductivity and the lowest activation energy are obtained in LLZ-Mg-2 x with x = 0.05, being 0.291 mS/cm at 293 K and 0.254 eV, respectively.
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Jiang Y. et al. Investigation of Mg2+, Sc3+ and Zn2+ doping effects on densification and ionic conductivity of low-temperature sintered Li7La3Zr2O12 garnets // Solid State Ionics. 2017. Vol. 300. pp. 73-77.
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Jiang Y., Zhu X., Qin S., Ling M., Zhu J. Investigation of Mg2+, Sc3+ and Zn2+ doping effects on densification and ionic conductivity of low-temperature sintered Li7La3Zr2O12 garnets // Solid State Ionics. 2017. Vol. 300. pp. 73-77.
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TY - JOUR
DO - 10.1016/j.ssi.2016.12.005
UR - https://doi.org/10.1016/j.ssi.2016.12.005
TI - Investigation of Mg2+, Sc3+ and Zn2+ doping effects on densification and ionic conductivity of low-temperature sintered Li7La3Zr2O12 garnets
T2 - Solid State Ionics
AU - Jiang, Yue
AU - Zhu, Xiaohong
AU - Qin, Shiying
AU - Ling, Mingen
AU - Zhu, Jiliang
PY - 2017
DA - 2017/02/01 00:00:00
PB - Elsevier
SP - 73-77
VL - 300
SN - 0167-2738
ER -
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@article{2017_Jiang,
author = {Yue Jiang and Xiaohong Zhu and Shiying Qin and Mingen Ling and Jiliang Zhu},
title = {Investigation of Mg2+, Sc3+ and Zn2+ doping effects on densification and ionic conductivity of low-temperature sintered Li7La3Zr2O12 garnets},
journal = {Solid State Ionics},
year = {2017},
volume = {300},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.ssi.2016.12.005},
pages = {73--77},
doi = {10.1016/j.ssi.2016.12.005}
}