Solid State Ionics, volume 315, pages 7-13

Graphene oxide as a filler to improve the performance of PAN-LiClO4 flexible solid polymer electrolyte

Weishang Jia ¹

Zhiling Li ¹

Zhenrui Wu ¹

Xuemei Liu ¹

Bo Wu ¹

Y. H. Wang ²

Ya Cao ³

Jingze Li ^{1, 4}

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State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Microelectronics and Solid-State Electronics, University of Electronic Science and Technology of China (UESTC), Chengdu 610054, China |

Department of Chemistry and Biology, University of Electronic Science and Technology of China Zhongshan Institute, Zhongshan 528402, China) |

State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu, 610065, China |

⁴

State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China |

Publication type: Journal Article

Publication date: 2018-02-01

Elsevier

Journal: Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor: 3.2

ISSN: 01672738

DOI: 10.1016/j.ssi.2017.11.026

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General Chemistry

Condensed Matter Physics

General Materials Science

Abstract

Solid polymer electrolytes (SPEs) show structural flexibility and safety to meet the requirements of lithium battery applications. However, SPEs usually have a low ionic conductivity at room temperature. In this study, in order to improve the ionic conductivity, we add graphene oxide (GO) as a nano-filler into LiClO4-polyacrylonitrile (PAN) type SPEs with various weight percentages. The ionic conductivity of the composite SPE containing 1.0 wt% GO has reached 4.0 × 10− 4 S cm− 1 at 30 °C, which is one order of magnitude higher than the bare one (2.2 × 10− 5 S cm− 1 at 30 °C). Meanwhile, the activation energy has reduced from 2.31 to 1.03 eV and the tensile modulus has increased from 37 to 80 MPa. This improvement is mainly ascribed to the functional groups ( OH, COOH, C O, COC, et al.) in GO that can alleviate the polarity of “ C N:”, which makes the polymer softer and facilitates the dissociation of LiClO4 in PAN matrix. Moreover, the LiFePO4 (LFP) cell with 1.0 wt% GO-SPE as electrolyte shows a satisfactory average discharge capacity of 166 mAh g− 1 at 0.2C, which is better than the performance in the GO-free type cell (136 mAh g− 1).

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Jia W. et al. Graphene oxide as a filler to improve the performance of PAN-LiClO4 flexible solid polymer electrolyte // Solid State Ionics. 2018. Vol. 315. pp. 7-13.

GOST all authors (up to 50) Copy

Jia W., Li Z., Wu Z., Liu X., Wu B., Wang Y. H., Cao Ya., Li J. Graphene oxide as a filler to improve the performance of PAN-LiClO4 flexible solid polymer electrolyte // Solid State Ionics. 2018. Vol. 315. pp. 7-13.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.ssi.2017.11.026

UR - https://doi.org/10.1016/j.ssi.2017.11.026

TI - Graphene oxide as a filler to improve the performance of PAN-LiClO4 flexible solid polymer electrolyte

T2 - Solid State Ionics

AU - Jia, Weishang

AU - Li, Zhiling

AU - Wu, Zhenrui

AU - Liu, Xuemei

AU - Wu, Bo

AU - Wang, Y. H.

AU - Cao, Ya

AU - Li, Jingze

PY - 2018

DA - 2018/02/01 00:00:00

PB - Elsevier

SP - 7-13

VL - 315

SN - 0167-2738

ER -

BibTex

Cite this

BibTex Copy

@article{2018_Jia,

author = {Weishang Jia and Zhiling Li and Zhenrui Wu and Xuemei Liu and Bo Wu and Y. H. Wang and Ya Cao and Jingze Li},

title = {Graphene oxide as a filler to improve the performance of PAN-LiClO4 flexible solid polymer electrolyte},

journal = {Solid State Ionics},

year = {2018},

volume = {315},

publisher = {Elsevier},

month = {feb},

url = {https://doi.org/10.1016/j.ssi.2017.11.026},

pages = {7--13},

doi = {10.1016/j.ssi.2017.11.026}

}

Found error?

Publisher

Elsevier

Journal

Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor

3.2

ISSN

01672738 (Print)