Solid State Ionics, volume 314, pages 92-97

Improved room temperature ionic conductivity of Ta and Ca doped Li7La3Zr2O12 via a modified solution method

Chen XIAOLAN ¹

Tianxiang Cao ¹

Mingzhe Xue ¹

Hong Lv ¹

Bing Li ¹

Cunman Zhang ¹

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Clean Energy Automotive Engineering Center, School of Automotive Studies, Tongji University, Shanghai, 201804, China |

Publication type: Journal Article

Publication date: 2018-01-01

Elsevier

Journal: Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor: 3.2

ISSN: 01672738

DOI: 10.1016/j.ssi.2017.11.027

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General Chemistry

Condensed Matter Physics

General Materials Science

Abstract

Ta and Ca doped Li7La3Zr2O12 is synthesized via a modified solution method without producing toxic NOx. Li7 − x + yCayLa3-yZr2 − xTaxO12 series with x range from 0 to 2 and y range from 0 to 0.05 are prepared and their ionic conductivities are found to be greatly enhanced by doping Ta and Ca to a certain amount. The optimized amount of Ta doped in Li7 − xLa3Zr2 − xTaxO12 is found to be x = 0.6, corresponding to a total ionic conductivity of 1.95 × 10− 4 S cm− 1. When further doped with Ca, a synergetic effect from Ta and Ca is observed and a high ionic conductivity of 2.84 × 10− 4 S cm− 1 is achieved in Li6.45Ca0.05La2.95Ta0.6Zr1.4O12. The simple solution method proposed in this work is considered to be potentially applied as a general methodology for synthesizing metal doped Li7La3Zr2O12.

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XIAOLAN C. et al. Improved room temperature ionic conductivity of Ta and Ca doped Li7La3Zr2O12 via a modified solution method // Solid State Ionics. 2018. Vol. 314. pp. 92-97.

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XIAOLAN C., Cao T., Xue M., Lv H., Li B., Zhang C. Improved room temperature ionic conductivity of Ta and Ca doped Li7La3Zr2O12 via a modified solution method // Solid State Ionics. 2018. Vol. 314. pp. 92-97.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.ssi.2017.11.027

UR - https://doi.org/10.1016/j.ssi.2017.11.027

TI - Improved room temperature ionic conductivity of Ta and Ca doped Li7La3Zr2O12 via a modified solution method

T2 - Solid State Ionics

AU - XIAOLAN, Chen

AU - Cao, Tianxiang

AU - Xue, Mingzhe

AU - Lv, Hong

AU - Li, Bing

AU - Zhang, Cunman

PY - 2018

DA - 2018/01/01 00:00:00

PB - Elsevier

SP - 92-97

VL - 314

SN - 0167-2738

ER -

BibTex

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BibTex Copy

@article{2018_XIAOLAN,

author = {Chen XIAOLAN and Tianxiang Cao and Mingzhe Xue and Hong Lv and Bing Li and Cunman Zhang},

title = {Improved room temperature ionic conductivity of Ta and Ca doped Li7La3Zr2O12 via a modified solution method},

journal = {Solid State Ionics},

year = {2018},

volume = {314},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/j.ssi.2017.11.027},

pages = {92--97},

doi = {10.1016/j.ssi.2017.11.027}

}

Found error?

Publisher

Elsevier

Journal

Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor

3.2

ISSN

01672738 (Print)