Solid State Ionics, volume 317, pages 122-126

Ionic conductivity and crystallization process in the Li2S–P2S5 glass electrolyte

Hirofumi Tsukasaki ¹

Shigeo Mori ¹

Shinya Shiotani ²

Hideyuki Yamamura ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University 1-1, Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan |

Battery Material Engineering & Research Div., Toyota Motor Corporation, Susono, Shizuoka 410-1193, Japan |

Publication type: Journal Article

Publication date: 2018-04-01

Elsevier

Journal: Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor: 3.2

ISSN: 01672738

DOI: 10.1016/j.ssi.2018.01.010

Copy DOI

General Chemistry

Condensed Matter Physics

General Materials Science

Abstract

The ionic conductivity of the Li2S–P2S5 glass electrolyte systems strongly depends on the type of precipitated crystalline phases and heat-treatment conditions. To clarify the correlation between ionic conductivity and crystallization behavior, a specific observation technique to visualize the precipitated nanocrystallites via transmission electron microscopy (TEM), and a quantitative method for evaluating the crystallization degree are developed. The 75Li2S·25P2S5 glass exhibits a high conductivity of approximately 7.5 × 10−4 S/cm at a sintering temperature between 120 °C and 180 °C. Above 180 °C, however, conductivity sharply decreases to 1.8 × 10−4 S/cm. In situ TEM observation reveals that this is attributed to the crystallization of the glasses. The crystallization process is mainly characterized by the formation of β-Li3PS4 nanocrystallites precipitated above 180 °C whose size remains intact during further heating until 250 °C. As a result, to achieve high ionic conductivity in the 75Li2S·25P2S5 glass, it is important to realize an amorphous state with the presence of nanocrystallites that would yield a crystallinity degree lower than 5%.

By date By citations

Top-30

Citations by journals

	1 2 3 4 5 6 7
Solid State Ionics	Solid State Ionics, 7, 11.86% Solid State Ionics 7 publications, 11.86%
Journal of Power Sources	Journal of Power Sources, 5, 8.47% Journal of Power Sources 5 publications, 8.47%
Advanced Energy Materials	Advanced Energy Materials, 5, 8.47% Advanced Energy Materials 5 publications, 8.47%
ACS applied materials & interfaces	ACS applied materials & interfaces, 4, 6.78% ACS applied materials & interfaces 4 publications, 6.78%
Journal of Non-Crystalline Solids	Journal of Non-Crystalline Solids, 3, 5.08% Journal of Non-Crystalline Solids 3 publications, 5.08%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 3, 5.08% Journal of Physical Chemistry C 3 publications, 5.08%
Energy Storage Materials	Energy Storage Materials, 2, 3.39% Energy Storage Materials 2 publications, 3.39%
Ceramics International	Ceramics International, 2, 3.39% Ceramics International 2 publications, 3.39%
Journal of the American Chemical Society	Journal of the American Chemical Society, 2, 3.39% Journal of the American Chemical Society 2 publications, 3.39%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 2, 3.39% Journal of Materials Chemistry A 2 publications, 3.39%
Chemistry of Materials	Chemistry of Materials, 1, 1.69% Chemistry of Materials 1 publication, 1.69%
Nature Communications	Nature Communications, 1, 1.69% Nature Communications 1 publication, 1.69%
Electrochemistry	Electrochemistry, 1, 1.69% Electrochemistry 1 publication, 1.69%
Materials Transactions	Materials Transactions, 1, 1.69% Materials Transactions 1 publication, 1.69%
Journal of the Ceramic Society of Japan	Journal of the Ceramic Society of Japan, 1, 1.69% Journal of the Ceramic Society of Japan 1 publication, 1.69%
Sustainable Materials and Technologies	Sustainable Materials and Technologies, 1, 1.69% Sustainable Materials and Technologies 1 publication, 1.69%
Advanced Powder Technology	Advanced Powder Technology, 1, 1.69% Advanced Powder Technology 1 publication, 1.69%
eTransportation	eTransportation, 1, 1.69% eTransportation 1 publication, 1.69%
Nanotechnology	Nanotechnology, 1, 1.69% Nanotechnology 1 publication, 1.69%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 1, 1.69% Journal of Alloys and Compounds 1 publication, 1.69%
Materials Today Nano	Materials Today Nano, 1, 1.69% Materials Today Nano 1 publication, 1.69%
Journal of the American Ceramic Society	Journal of the American Ceramic Society, 1, 1.69% Journal of the American Ceramic Society 1 publication, 1.69%
Energy Technology	Energy Technology, 1, 1.69% Energy Technology 1 publication, 1.69%
ACS Omega	ACS Omega, 1, 1.69% ACS Omega 1 publication, 1.69%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 1.69% ACS Applied Energy Materials 1 publication, 1.69%
Sustainable Energy and Fuels	Sustainable Energy and Fuels, 1, 1.69% Sustainable Energy and Fuels 1 publication, 1.69%
Microscopy (Oxford, England)	Microscopy (Oxford, England), 1, 1.69% Microscopy (Oxford, England) 1 publication, 1.69%
Open Engineering	Open Engineering, 1, 1.69% Open Engineering 1 publication, 1.69%
Batteries	Batteries, 1, 1.69% Batteries 1 publication, 1.69%
	1 2 3 4 5 6 7

Citations by publishers

	5 10 15 20 25
Elsevier	Elsevier, 24, 40.68% Elsevier 24 publications, 40.68%
American Chemical Society (ACS)	American Chemical Society (ACS), 12, 20.34% American Chemical Society (ACS) 12 publications, 20.34%
Wiley	Wiley, 9, 15.25% Wiley 9 publications, 15.25%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 3, 5.08% Royal Society of Chemistry (RSC) 3 publications, 5.08%
Springer Nature	Springer Nature, 1, 1.69% Springer Nature 1 publication, 1.69%
The Electrochemical Society of Japan	The Electrochemical Society of Japan, 1, 1.69% The Electrochemical Society of Japan 1 publication, 1.69%
Japan Institute of Metals and Materials	Japan Institute of Metals and Materials, 1, 1.69% Japan Institute of Metals and Materials 1 publication, 1.69%
Ceramic Society of Japan	Ceramic Society of Japan, 1, 1.69% Ceramic Society of Japan 1 publication, 1.69%
IOP Publishing	IOP Publishing, 1, 1.69% IOP Publishing 1 publication, 1.69%
Oxford University Press	Oxford University Press, 1, 1.69% Oxford University Press 1 publication, 1.69%
Walter de Gruyter	Walter de Gruyter, 1, 1.69% Walter de Gruyter 1 publication, 1.69%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 1.69% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 1.69%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.69% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.69%
	5 10 15 20 25

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0],"imageUrls":["","","","","","",""],"datasets":[{"label":"Citations number","data":[3,8,7,11,11,13,6],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["5.08","13.56","11.86","18.64","18.64","22.03","10.17"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Solid State Ionics","Journal of Power Sources","Advanced Energy Materials","ACS applied materials & interfaces","Journal of Non-Crystalline Solids","Journal of Physical Chemistry C","Energy Storage Materials","Ceramics International","Journal of the American Chemical Society","Journal of Materials Chemistry A","Chemistry of Materials","Nature Communications","Electrochemistry","Materials Transactions","Journal of the Ceramic Society of Japan","Sustainable Materials and Technologies","Advanced Powder Technology","eTransportation","Nanotechnology","Journal of Alloys and Compounds","Materials Today Nano","Journal of the American Ceramic Society","Energy Technology","ACS Omega","ACS Applied Energy Materials","Sustainable Energy and Fuels","Microscopy (Oxford, England)","Open Engineering","Batteries"],"ids":[12542,14844,22475,1458,17924,8859,3858,15103,4813,14919,6428,3231,7343,3924,12166,5809,4165,25487,16187,4015,1122,24329,20046,18901,6419,14712,24667,17973,19798],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/JWkRrt4U4oPa4E6W7adkLpyIMTatGmlu51Ge50zC_medium.webp","\/storage\/images\/resized\/zQzbIl4hd4Cvotqxegq4iYlWwKtIuOpkurp0iZgO_medium.webp","\/storage\/images\/resized\/wPdRrJc5VQu0TUaMSWG046vuH1WyplWqqs44TF51_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/yNSijlgQghQF53VZuyFLA30CKDe4j3HK74Vtpnxa_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp"],"datasets":[{"label":"","data":[7,5,5,4,3,3,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[11.86,8.47,8.47,6.78,5.08,5.08,3.39,3.39,3.39,3.39,1.69,1.69,1.69,1.69,1.69,1.69,1.69,1.69,1.69,1.69,1.69,1.69,1.69,1.69,1.69,1.69,1.69,1.69,1.69],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","American Chemical Society (ACS)","Wiley","Royal Society of Chemistry (RSC)","Springer Nature","The Electrochemical Society of Japan","Japan Institute of Metals and Materials","Ceramic Society of Japan","IOP Publishing","Oxford University Press","Walter de Gruyter","Multidisciplinary Digital Publishing Institute (MDPI)","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[17,40,11,123,8,7035,1425,3755,2075,19,4,202,9422],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/JWkRrt4U4oPa4E6W7adkLpyIMTatGmlu51Ge50zC_medium.webp","\/storage\/images\/resized\/zQzbIl4hd4Cvotqxegq4iYlWwKtIuOpkurp0iZgO_medium.webp","\/storage\/images\/resized\/wPdRrJc5VQu0TUaMSWG046vuH1WyplWqqs44TF51_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/yNSijlgQghQF53VZuyFLA30CKDe4j3HK74Vtpnxa_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[24,12,9,3,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[40.68,20.34,15.25,5.08,1.69,1.69,1.69,1.69,1.69,1.69,1.69,1.69,1.69],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,2,0,0],"percentage":["0","0","0","0","3.39","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,1,0,0,0,0,0],"percentage":["0","1.69","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,1,2,4,1,5,0],"percentage":["1.69","1.69","3.39","6.78","1.69","8.47","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[2,6,5,5,8,8,6],"percentage":["3.39","10.17","8.47","8.47","13.56","13.56","10.17"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,2,0,0,0],"percentage":["0","0","0","3.39","0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,1,1,0,0],"percentage":["0","0","0","1.69","1.69","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,1,0,0,1,1,0],"percentage":["0","1.69","0","0","1.69","1.69","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,3,4,3,0,3,1],"percentage":["0","5.08","6.78","5.08","0","5.08","1.69"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[3,4,3,5,8,9,5],"percentage":["5.08","6.78","5.08","8.47","13.56","15.25","8.47"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,2,1,0,0],"percentage":["0","0","0","3.39","1.69","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Tsukasaki H. et al. Ionic conductivity and crystallization process in the Li2S–P2S5 glass electrolyte // Solid State Ionics. 2018. Vol. 317. pp. 122-126.

GOST all authors (up to 50) Copy

Tsukasaki H., Mori S., Shiotani S., Yamamura H. Ionic conductivity and crystallization process in the Li2S–P2S5 glass electrolyte // Solid State Ionics. 2018. Vol. 317. pp. 122-126.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.ssi.2018.01.010

UR - https://doi.org/10.1016/j.ssi.2018.01.010

TI - Ionic conductivity and crystallization process in the Li2S–P2S5 glass electrolyte

T2 - Solid State Ionics

AU - Tsukasaki, Hirofumi

AU - Mori, Shigeo

AU - Shiotani, Shinya

AU - Yamamura, Hideyuki

PY - 2018

DA - 2018/04/01 00:00:00

PB - Elsevier

SP - 122-126

VL - 317

SN - 0167-2738

ER -

BibTex

Cite this

BibTex Copy

@article{2018_Tsukasaki,

author = {Hirofumi Tsukasaki and Shigeo Mori and Shinya Shiotani and Hideyuki Yamamura},

title = {Ionic conductivity and crystallization process in the Li2S–P2S5 glass electrolyte},

journal = {Solid State Ionics},

year = {2018},

volume = {317},

publisher = {Elsevier},

month = {apr},

url = {https://doi.org/10.1016/j.ssi.2018.01.010},

pages = {122--126},

doi = {10.1016/j.ssi.2018.01.010}

}

Found error?

Publisher

Elsevier

Journal

Solid State Ionics

Quartile SCImago

Quartile WOS

Impact factor

3.2

ISSN

01672738 (Print)