Solid State Ionics

, volume 333 , pages 18-29

Effects of conductive binder on the electrochemical performance of lithium titanate anodes

S. N. Eliseeva ¹

E V Shkreba ¹

M. A. Kamenskii ¹

E G Tolstopjatova ¹

Rudolf Holze ^{1, 2, 3}

V. V. Kondratiev ¹

Hide authors affiliations Show authors affiliations: 3 affiliations

Department of Electrochemistry, Institute of Chemistry, Saint Petersburg State University, 7/9 Universitetskaya nab., St. Petersburg 199034, Russian Federation |

Chemnitz University of Technology, Institute of Chemistry, AG Elektrochemie, 62 Strasse der Nationen, Chemnitz D-09111, Germany |

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Energy Science and Technology and Institute of Advanced Materials, Nanjing Tech University, Nanjing 211816, Jiangsu Province, China |

Publication type: Journal Article

Publication date: 2019-05-01

Elsevier

Solid State Ionics

scimago Q2

wos Q2

SJR: 0.672

CiteScore: 5.3

Impact factor: 3.3

ISSN: 01672738, 18727689

DOI: 10.1016/j.ssi.2019.01.011

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General Chemistry

Condensed Matter Physics

General Materials Science

Abstract

An eco-friendly water-based binder consisting of a combination of intrinsically conducting polymer poly-3,4-ethylenedioxythiopene:polystyrene sulfonate (PEDOT:PSS) dispersion and carboxymethylcellulose (СМС) proposed as component of Li4Ti5O12-based negative electrode has been studied at different compositions and compared with conventional PVDF binder. Morphology and structure of the composite materials were investigated by X-ray diffraction, scanning electron microscopy and EDX analysis. Electrochemical characterization was performed by galvanostatic charge-discharge experiments, cyclic voltammetry and impedance spectroscopy. The electrode with combined PEDOT:PSS/CMC binder has superior properties, in particular increased specific capacity and improved C-rate performance during charge-discharge. By using PEDOT:PSS/CMC binder instead of PVDF, the practical specific capacity was increased up to 14% (157 mAh g−1 at 0.2 C, normalized to total electrode mass). Highest stability during long cycling was observed for Li4Ti5O12-electrode with this binder at

Found

5 citations

Kamenskii Mikhail

37 publications, 305 citations

h-index: 10

Saint Petersburg State University

3 citations

Volkov Alexey

40 publications, 348 citations, 26 reviews

h-index: 12

Saint Petersburg State University

Research interests

Electrochemistry

Lithium-ion batteries

Supercapacitors

2 citations

Antipov Evgeny

DSc in Chemistry, professor, full member of the Russian Academy of Sciences

464 publications, 10 624 citations, 29 reviews

h-index: 49

Lomonosov Moscow State University

Skolkovo Institute of Science and Technology

1 citation

Karpushkin Evgeny

🥼

PhD in Physics and Mathematics, associate professor

59 publications, 707 citations

h-index: 14

Lomonosov Moscow State University

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GOST Copy

Eliseeva S. N. et al. Effects of conductive binder on the electrochemical performance of lithium titanate anodes // Solid State Ionics. 2019. Vol. 333. pp. 18-29.

GOST all authors (up to 50) Copy

Eliseeva S. N., Shkreba E. V., Kamenskii M. A., Tolstopjatova E. G., Holze R., Kondratiev V. V. Effects of conductive binder on the electrochemical performance of lithium titanate anodes // Solid State Ionics. 2019. Vol. 333. pp. 18-29.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.ssi.2019.01.011

UR - https://doi.org/10.1016/j.ssi.2019.01.011

TI - Effects of conductive binder on the electrochemical performance of lithium titanate anodes

T2 - Solid State Ionics

AU - Eliseeva, S. N.

AU - Shkreba, E V

AU - Kamenskii, M. A.

AU - Tolstopjatova, E G

AU - Holze, Rudolf

AU - Kondratiev, V. V.

PY - 2019

DA - 2019/05/01

PB - Elsevier

SP - 18-29

VL - 333

SN - 0167-2738

SN - 1872-7689

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2019_Eliseeva,

author = {S. N. Eliseeva and E V Shkreba and M. A. Kamenskii and E G Tolstopjatova and Rudolf Holze and V. V. Kondratiev},

title = {Effects of conductive binder on the electrochemical performance of lithium titanate anodes},

journal = {Solid State Ionics},

year = {2019},

volume = {333},

publisher = {Elsevier},

month = {may},

url = {https://doi.org/10.1016/j.ssi.2019.01.011},

pages = {18--29},

doi = {10.1016/j.ssi.2019.01.011}

}

Publisher

Elsevier

Journal

Solid State Ionics

scimago Q2

wos Q2

SJR

0.672

CiteScore

5.3

Impact factor

3.3

ISSN

01672738 (Print)

18727689

Labs

Electrode materials for metal-ion batteries, supercapacitors and redox batteries

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