Solid State Ionics, volume 378, pages 115888
Electrochemical stability of a NASICON solid electrolyte from the lithium aluminum germanium phosphate (LAGP) series
Publication type: Journal Article
Publication date: 2022-05-01
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 glass-ceramics from NASICON series was synthesized using two different methods: single heat treatment and glass sintering with concurrent crystallization of a pressed pellet, which exhibit ionic conductivity of 4.15 × 10 −4 S cm −1 . The electrochemical stability window was investigated by cyclic voltammetry, utilizing a mixture of powder solid electrolyte, carbon, and binder as the working electrode, resulting in the Li/LAGP/LAGP+C/Au configuration. As a comparison, conventional set-up for cyclic voltammetry was also used, resulting in the Li/LAGP/Au setup. An electrochemical stability window around 3.5 V was found. • Electrochemical stability window of NASICON Lithium – aluminum – germanium – phosphate (x = 0,5). • Sintering with concurrent crystallization of glass pellets with subsequent crystallization. • Anodic and cathodic limits vary depending on working electrode configuration. • Conventional and modified cyclic voltammetry of LAGP.
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- We do not take into account publications without a DOI.
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Zallocco V.M. et al. Electrochemical stability of a NASICON solid electrolyte from the lithium aluminum germanium phosphate (LAGP) series // Solid State Ionics. 2022. Vol. 378. p. 115888.
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Zallocco V.M., Freitas J.M., Bocchi N., Rodrigues A.C. Electrochemical stability of a NASICON solid electrolyte from the lithium aluminum germanium phosphate (LAGP) series // Solid State Ionics. 2022. Vol. 378. p. 115888.
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TY - JOUR
DO - 10.1016/j.ssi.2022.115888
UR - https://doi.org/10.1016/j.ssi.2022.115888
TI - Electrochemical stability of a NASICON solid electrolyte from the lithium aluminum germanium phosphate (LAGP) series
T2 - Solid State Ionics
AU - Zallocco, V M
AU - Freitas, J M
AU - Bocchi, N
AU - Rodrigues, A C
PY - 2022
DA - 2022/05/01 00:00:00
PB - Elsevier
SP - 115888
VL - 378
SN - 0167-2738
ER -
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@article{2022,
author = {V M Zallocco and J M Freitas and N Bocchi and A C Rodrigues},
title = {Electrochemical stability of a NASICON solid electrolyte from the lithium aluminum germanium phosphate (LAGP) series},
journal = {Solid State Ionics},
year = {2022},
volume = {378},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/j.ssi.2022.115888},
pages = {115888},
doi = {10.1016/j.ssi.2022.115888}
}