volume 108 pages 77-84

Catalytic cyclometallation in steroid chemistry IV: Efficient method for the synthesis of tetrahydrothiophene, tetrahydroselenophen and cyclopentanone derivatives of (5α)-cholestane

Publication typeJournal Article
Publication date2016-04-01
scimago Q2
wos Q3
SJR0.620
CiteScore4.3
Impact factor2.3
ISSN0039128X, 18785867
Organic Chemistry
Biochemistry
Molecular Biology
Pharmacology
Clinical Biochemistry
Endocrinology
Abstract
Catalytic cycloalumination of (3β,5α)-3-vinylcholestane and (3α,5α)-3-allylcholestane with Et3Al catalyzed by Cp2ZrCl2 was performed for the first time to give previously unknown aluminacyclopentanes in ∼90% yield; these products were converted in situ to carbo- and heterocyclic (5α)-cholestane derivatives.
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D'yakonov V. A. et al. Catalytic cyclometallation in steroid chemistry IV: Efficient method for the synthesis of tetrahydrothiophene, tetrahydroselenophen and cyclopentanone derivatives of (5α)-cholestane // Steroids. 2016. Vol. 108. pp. 77-84.
GOST all authors (up to 50) Copy
D'yakonov V. A., Tuktarova R. A., Islamov I. I., Khalilov L. M., Dzhemilev U. M. Catalytic cyclometallation in steroid chemistry IV: Efficient method for the synthesis of tetrahydrothiophene, tetrahydroselenophen and cyclopentanone derivatives of (5α)-cholestane // Steroids. 2016. Vol. 108. pp. 77-84.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.steroids.2016.01.015
UR - https://doi.org/10.1016/j.steroids.2016.01.015
TI - Catalytic cyclometallation in steroid chemistry IV: Efficient method for the synthesis of tetrahydrothiophene, tetrahydroselenophen and cyclopentanone derivatives of (5α)-cholestane
T2 - Steroids
AU - D'yakonov, Vladimir A
AU - Tuktarova, Regina A.
AU - Islamov, Ilgiz I
AU - Khalilov, Leonard M.
AU - Dzhemilev, Usein M
PY - 2016
DA - 2016/04/01
PB - Elsevier
SP - 77-84
VL - 108
PMID - 26827630
SN - 0039-128X
SN - 1878-5867
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2016_D'yakonov,
author = {Vladimir A D'yakonov and Regina A. Tuktarova and Ilgiz I Islamov and Leonard M. Khalilov and Usein M Dzhemilev},
title = {Catalytic cyclometallation in steroid chemistry IV: Efficient method for the synthesis of tetrahydrothiophene, tetrahydroselenophen and cyclopentanone derivatives of (5α)-cholestane},
journal = {Steroids},
year = {2016},
volume = {108},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.steroids.2016.01.015},
pages = {77--84},
doi = {10.1016/j.steroids.2016.01.015}
}