Surface and Coatings Technology, volume 481, pages 130671
Li1.3Al0.3Ti1.7(PO4)3 (LATP) solid electrolytes synthesized by microwave-assisted hydrothermal reactions for Li all-solid-state battery applications
Publication type: Journal Article
Publication date: 2024-04-01
Journal:
Surface and Coatings Technology
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.4
ISSN: 02578972
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Condensed Matter Physics
Surfaces and Interfaces
Abstract
Sub-micron LATP solid electrolytes have been prepared via a facile microwave-assisted hydrothermal method. The structure and ionic conductivity of LATP has been investigated as a function of hydrothermal synthesis temperature by powder X-ray diffraction (XRD), thermal analysis, scanning electron microscopy (SEM), and electrochemical impedance spectroscopy (EIS). The hydrothermal synthesis temperature is pivotal in controlling the uniformity of the LATP particle size distribution and the surface morphology of the electrolyte. Optimal LATP pellets prepared from powder synthesized at 180 °C exhibit an ionic conductivity of 1.4 × 10−4 S cm−1 at 298 K, while variable temperature measurements yielded activation energy of 0.253 eV for Li diffusion. These favorable values could reflect the uniform particle size distribution, high crystallinity and a relative density as high as 97 %. The optimum electrolyte material was applied in an NCM523/LATP/Graphite pouch cell, which demonstrated a stable capacity (≥ 92.5 % at a Coulombic efficiency of ~100 %) for >400 cycles. The results indicate that LATP synthesized by microwave-assisted hydrothermal methods performs very effectively as a solid electrolyte and is a credible candidate for all-solid-state LIBs.
Top-30
Citations by journals
|
1
|
|
|
Batteries
1 publication, 50%
|
|
|
Russian Chemical Reviews
1 publication, 50%
|
|
|
1
|
Citations by publishers
|
1
|
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 50%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 50%
|
|
|
1
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2024],"ids":[0],"codes":[0],"imageUrls":[""],"datasets":[{"label":"Citations number","data":[2],"backgroundColor":["#3B82F6"],"percentage":["100"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Batteries","Russian Chemical Reviews"],"ids":[19798,23802],"codes":[0,0],"imageUrls":["\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[1,1],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":[50,50],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Multidisciplinary Digital Publishing Institute (MDPI)","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[202,9422],"codes":[0,0],"imageUrls":["\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[1,1],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":[50,50],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0],"percentage":["0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0],"percentage":["0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1],"percentage":["50"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1],"percentage":["50"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0],"percentage":["0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0],"percentage":["0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0],"percentage":["0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1],"percentage":["50"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1],"percentage":["50"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0],"percentage":["0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Yu C. et al. Li1.3Al0.3Ti1.7(PO4)3 (LATP) solid electrolytes synthesized by microwave-assisted hydrothermal reactions for Li all-solid-state battery applications // Surface and Coatings Technology. 2024. Vol. 481. p. 130671.
GOST all authors (up to 50)
Copy
Yu C., Yu C., Gregory D. H., Liu W. Li1.3Al0.3Ti1.7(PO4)3 (LATP) solid electrolytes synthesized by microwave-assisted hydrothermal reactions for Li all-solid-state battery applications // Surface and Coatings Technology. 2024. Vol. 481. p. 130671.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.surfcoat.2024.130671
UR - https://linkinghub.elsevier.com/retrieve/pii/S0257897224003013
TI - Li1.3Al0.3Ti1.7(PO4)3 (LATP) solid electrolytes synthesized by microwave-assisted hydrothermal reactions for Li all-solid-state battery applications
T2 - Surface and Coatings Technology
AU - Yu, Chan-Wei
AU - Gregory, Duncan H.
AU - Liu, Wei-Ren
AU - Yu, Cheng-En
PY - 2024
DA - 2024/04/01 00:00:00
PB - Elsevier
SP - 130671
VL - 481
SN - 0257-8972
ER -
Cite this
BibTex
Copy
@article{2024_Yu,
author = {Chan-Wei Yu and Duncan H. Gregory and Wei-Ren Liu and Cheng-En Yu},
title = {Li1.3Al0.3Ti1.7(PO4)3 (LATP) solid electrolytes synthesized by microwave-assisted hydrothermal reactions for Li all-solid-state battery applications},
journal = {Surface and Coatings Technology},
year = {2024},
volume = {481},
publisher = {Elsevier},
month = {apr},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0257897224003013},
pages = {130671},
doi = {10.1016/j.surfcoat.2024.130671}
}