Comparison of photophysicochemical properties of hexaphenoxycyclotriphosphazenyl-substituted metal-free, mono- and bis-lutetium phthalocyanines
Publication type: Journal Article
Publication date: 2010-03-01
scimago Q1
wos Q2
SJR: 0.787
CiteScore: 8.3
Impact factor: 4.6
ISSN: 03796779
Materials Chemistry
Metals and Alloys
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanical Engineering
Mechanics of Materials
Abstract
The aim of this study is to compare the photophysicochemical properties of hexaphenoxycyclotriphosphazenyl-substituted metal-free (1), mono-(phthalocyaninato) lutetium(III) (2) [LuIII(AcO)(Pc)] (Pc = phthalocyaninato, AcO = acetate) and bis-(phthalocyaninato) lutetium(III) (3) [LuIIIPc2]. The synthesis and characterization (using the elemental analysis, mass spectrometry, IR, 1H, and 31P NMR and UV–vis spectroscopy) of new compounds (2, 3) are described in this study. The electronic absorption and fluorescence spectral properties of compounds 1–3 are investigated. Photophysical (fluorescence quantum yields and lifetimes) and photochemical (singlet oxygen and photodegradation quantum yields) measurements are also studied on hexaphenoxycyclotriphosphazenyl-appended metal-free, mono- and bis-lutetium phthalocyanines in dimethylsulfoxide (DMSO). Photophysical and photochemical properties of phthalocyanines are very useful for photodynamic therapy (PDT) applications. Singlet oxygen quantum yields (ΦΔ) give an indication of the potential of the complexes as photosensitizers in PDT applications. Hexaphenoxycyclotriphosphazenyl-substituted mono-(phthalocyaninato) lutetium(III) complex (2) gave good singlet oxygen quantum yield (0.66) in DMSO. Thus, this complex shows potential as Type II photosensitizer for PDT of cancer.
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GOST
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Durmuş M. et al. Comparison of photophysicochemical properties of hexaphenoxycyclotriphosphazenyl-substituted metal-free, mono- and bis-lutetium phthalocyanines // Synthetic Metals. 2010. Vol. 160. No. 5-6. pp. 436-444.
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Durmuş M., Yeşilot S., Çoşut B., Gürek A. G., Kılıç A., Ahsen V. Comparison of photophysicochemical properties of hexaphenoxycyclotriphosphazenyl-substituted metal-free, mono- and bis-lutetium phthalocyanines // Synthetic Metals. 2010. Vol. 160. No. 5-6. pp. 436-444.
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TY - JOUR
DO - 10.1016/j.synthmet.2009.11.026
UR - https://doi.org/10.1016/j.synthmet.2009.11.026
TI - Comparison of photophysicochemical properties of hexaphenoxycyclotriphosphazenyl-substituted metal-free, mono- and bis-lutetium phthalocyanines
T2 - Synthetic Metals
AU - Durmuş, Mahmut
AU - Yeşilot, Serkan
AU - Çoşut, Bünyemin
AU - Gürek, Ayşe Gül
AU - Kılıç, Adem
AU - Ahsen, Vefa
PY - 2010
DA - 2010/03/01
PB - Elsevier
SP - 436-444
IS - 5-6
VL - 160
SN - 0379-6779
ER -
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BibTex (up to 50 authors)
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@article{2010_Durmuş,
author = {Mahmut Durmuş and Serkan Yeşilot and Bünyemin Çoşut and Ayşe Gül Gürek and Adem Kılıç and Vefa Ahsen},
title = {Comparison of photophysicochemical properties of hexaphenoxycyclotriphosphazenyl-substituted metal-free, mono- and bis-lutetium phthalocyanines},
journal = {Synthetic Metals},
year = {2010},
volume = {160},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.synthmet.2009.11.026},
number = {5-6},
pages = {436--444},
doi = {10.1016/j.synthmet.2009.11.026}
}
Cite this
MLA
Copy
Durmuş, Mahmut, et al. “Comparison of photophysicochemical properties of hexaphenoxycyclotriphosphazenyl-substituted metal-free, mono- and bis-lutetium phthalocyanines.” Synthetic Metals, vol. 160, no. 5-6, Mar. 2010, pp. 436-444. https://doi.org/10.1016/j.synthmet.2009.11.026.