Synthesis and characterization of poly(triphenylamine)s with electron-withdrawing trifluoromethyl side groups for emissive and hole-transporting layer
Publication type: Journal Article
Publication date: 2011-10-01
scimago Q1
wos Q2
SJR: 0.787
CiteScore: 8.3
Impact factor: 4.6
ISSN: 03796779
Materials Chemistry
Metals and Alloys
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanical Engineering
Mechanics of Materials
Abstract
Poly(triphenylamine)s with electron-withdrawing trifluoromethyl side groups were prepared to afford ambipolar type polymers that can be used as not only an emissive layer but also a hole-transporting layer for PLEDs. First, triphenylamine-based monomers with trifluoromethyl side group were prepared, such as N,N-diphenyl-4-(trifluoromethyl)benzeamine (3FTPA) and N,N-diphenyl-3,5-bis(trifluoromethyl)benzeamine (6FTPA). Next, they were brominated and bolorated and then utilized to prepare poly(triphenylamine)s via Suzuki coupling reaction. The resulting polymers were characterized by NMR, GC/MS, FT-IR, TGA and DSC, while optical and electrical properties were also measured by fluorescence spectroscopy, UV–vis spectroscopy, and cyclic voltammetry (CV). The polymers exhibited deep blue emission (422, 443 nm) and high T g s (225, 209 °C).
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Total citations:
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Citations from 2024:
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Kim G., Basarir F., Yoon T. Synthesis and characterization of poly(triphenylamine)s with electron-withdrawing trifluoromethyl side groups for emissive and hole-transporting layer // Synthetic Metals. 2011. Vol. 161. No. 19-20. pp. 2092-2096.
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Kim G., Basarir F., Yoon T. Synthesis and characterization of poly(triphenylamine)s with electron-withdrawing trifluoromethyl side groups for emissive and hole-transporting layer // Synthetic Metals. 2011. Vol. 161. No. 19-20. pp. 2092-2096.
Cite this
RIS
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TY - JOUR
DO - 10.1016/j.synthmet.2011.07.026
UR - https://doi.org/10.1016/j.synthmet.2011.07.026
TI - Synthesis and characterization of poly(triphenylamine)s with electron-withdrawing trifluoromethyl side groups for emissive and hole-transporting layer
T2 - Synthetic Metals
AU - Kim, Guntae
AU - Basarir, Fevzihan
AU - Yoon, Taeho
PY - 2011
DA - 2011/10/01
PB - Elsevier
SP - 2092-2096
IS - 19-20
VL - 161
SN - 0379-6779
ER -
Cite this
BibTex (up to 50 authors)
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@article{2011_Kim,
author = {Guntae Kim and Fevzihan Basarir and Taeho Yoon},
title = {Synthesis and characterization of poly(triphenylamine)s with electron-withdrawing trifluoromethyl side groups for emissive and hole-transporting layer},
journal = {Synthetic Metals},
year = {2011},
volume = {161},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.synthmet.2011.07.026},
number = {19-20},
pages = {2092--2096},
doi = {10.1016/j.synthmet.2011.07.026}
}
Cite this
MLA
Copy
Kim, Guntae, et al. “Synthesis and characterization of poly(triphenylamine)s with electron-withdrawing trifluoromethyl side groups for emissive and hole-transporting layer.” Synthetic Metals, vol. 161, no. 19-20, Oct. 2011, pp. 2092-2096. https://doi.org/10.1016/j.synthmet.2011.07.026.