Ni(II) and Cu(II) coordination polymers with rubeanic acid ligands as promising electrode materials for lithium and potassium batteries
E A Komissarova
1
,
Olga A Kraevaya
1
,
I. S. ZHIDKOV
2, 3
,
A. I. KUKHARENKO
2, 3
,
Nadezhda N Dremova
1
,
Yuliya V Baskakova
1
,
Alexander F. Shestakov
1, 4
,
Publication type: Journal Article
Publication date: 2023-03-01
scimago Q1
wos Q2
SJR: 0.787
CiteScore: 8.3
Impact factor: 4.6
ISSN: 03796779
Materials Chemistry
Metals and Alloys
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanical Engineering
Mechanics of Materials
Abstract
We report the synthesis of Ni(II) and Cu(II) coordination polymers with rubeanic acid ligands and their application as electrode materials in lithium and potassium batteries. Both designed polymers delivered specific discharge capacity of ∼100–106 mAh g−1 and demonstrate stable charge-discharge cycling at 1 A g−1 for at least 300 cycles. Furthermore, Ni-based coordination polymer showed decent performance in potassium batteries providing the specific discharge capacity of 138 mAh g−1 after 400 cycles at 0.5 A g−1. The electrode degradation pathways during the battery cycling were investigated using ex-situ FTIR and XPS spectroscopy.
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Komissarova E. A. et al. Ni(II) and Cu(II) coordination polymers with rubeanic acid ligands as promising electrode materials for lithium and potassium batteries // Synthetic Metals. 2023. Vol. 293. p. 117300.
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Komissarova E. A., Kraevaya O. A., ZHIDKOV I. S., KUKHARENKO A. I., Dremova N. N., Baskakova Y. V., Shestakov A. F., Troshin P. A. Ni(II) and Cu(II) coordination polymers with rubeanic acid ligands as promising electrode materials for lithium and potassium batteries // Synthetic Metals. 2023. Vol. 293. p. 117300.
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TY - JOUR
DO - 10.1016/j.synthmet.2023.117300
UR - https://doi.org/10.1016/j.synthmet.2023.117300
TI - Ni(II) and Cu(II) coordination polymers with rubeanic acid ligands as promising electrode materials for lithium and potassium batteries
T2 - Synthetic Metals
AU - Komissarova, E A
AU - Kraevaya, Olga A
AU - ZHIDKOV, I. S.
AU - KUKHARENKO, A. I.
AU - Dremova, Nadezhda N
AU - Baskakova, Yuliya V
AU - Shestakov, Alexander F.
AU - Troshin, Pavel A.
PY - 2023
DA - 2023/03/01
PB - Elsevier
SP - 117300
VL - 293
SN - 0379-6779
ER -
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@article{2023_Komissarova,
author = {E A Komissarova and Olga A Kraevaya and I. S. ZHIDKOV and A. I. KUKHARENKO and Nadezhda N Dremova and Yuliya V Baskakova and Alexander F. Shestakov and Pavel A. Troshin},
title = {Ni(II) and Cu(II) coordination polymers with rubeanic acid ligands as promising electrode materials for lithium and potassium batteries},
journal = {Synthetic Metals},
year = {2023},
volume = {293},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.synthmet.2023.117300},
pages = {117300},
doi = {10.1016/j.synthmet.2023.117300}
}