volume 128 pages 170-176

Magnetic dummy molecularly imprinted polymers based on multi-walled carbon nanotubes for rapid selective solid-phase extraction of 4-nonylphenol in aqueous samples

Publication typeJournal Article
Publication date2014-10-01
scimago Q1
wos Q1
SJR0.976
CiteScore11.0
Impact factor6.1
ISSN00399140, 18733573
Analytical Chemistry
Abstract
In this paper, a highly selective sample clean-up procedure combining magnetic dummy molecular imprinting with solid-phase extraction was developed for rapid separation and determination of 4-nonylphenol (NP) in the environmental water samples. The magnetic dummy molecularly imprinted polymers (mag-DMIPs) based on multi-walled carbon nanotubes were successfully synthesized with a surface molecular imprinting technique using 4-tert-octylphenol as the dummy template and tetraethylorthosilicate as the cross-linker. The maximum adsorption capacity of the mag-DMIPs for NP was 52.4 mg g(-1) and it took about 20 min to achieve the adsorption equilibrium. The mag-DMIPs exhibited the specific selective adsorption toward NP. Coupled with high performance liquid chromatography analysis, the mag-DMIPs were used to extract solid-phase and detect NP in real water samples successfully with the recoveries of 88.6-98.1%.
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GOST Copy
RAO W. et al. Magnetic dummy molecularly imprinted polymers based on multi-walled carbon nanotubes for rapid selective solid-phase extraction of 4-nonylphenol in aqueous samples // Talanta. 2014. Vol. 128. pp. 170-176.
GOST all authors (up to 50) Copy
RAO W., Cai R., Yin Y., Long F., Zhang Z. Magnetic dummy molecularly imprinted polymers based on multi-walled carbon nanotubes for rapid selective solid-phase extraction of 4-nonylphenol in aqueous samples // Talanta. 2014. Vol. 128. pp. 170-176.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.talanta.2014.04.087
UR - https://doi.org/10.1016/j.talanta.2014.04.087
TI - Magnetic dummy molecularly imprinted polymers based on multi-walled carbon nanotubes for rapid selective solid-phase extraction of 4-nonylphenol in aqueous samples
T2 - Talanta
AU - RAO, Wei
AU - Cai, Rong
AU - Yin, Yuli
AU - Long, Fang
AU - Zhang, Zhaohui
PY - 2014
DA - 2014/10/01
PB - Elsevier
SP - 170-176
VL - 128
PMID - 25059145
SN - 0039-9140
SN - 1873-3573
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2014_RAO,
author = {Wei RAO and Rong Cai and Yuli Yin and Fang Long and Zhaohui Zhang},
title = {Magnetic dummy molecularly imprinted polymers based on multi-walled carbon nanotubes for rapid selective solid-phase extraction of 4-nonylphenol in aqueous samples},
journal = {Talanta},
year = {2014},
volume = {128},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.talanta.2014.04.087},
pages = {170--176},
doi = {10.1016/j.talanta.2014.04.087}
}