Formation enthalpies and thermodynamics of some reactions of the Bi12.5R1.5ReO24.5 (R=Y, Nd, La) compounds
Publication type: Journal Article
Publication date: 2011-01-01
scimago Q2
wos Q2
SJR: 0.640
CiteScore: 6.2
Impact factor: 3.5
ISSN: 00406031, 1872762X
Physical and Theoretical Chemistry
Condensed Matter Physics
Instrumentation
Abstract
Solution calorimetry, using 2.0 M HCl (T = 298.15 K) as a solvent, is used to study the thermochemistry of Bi12.5R1.5ReO24.5 (R = Nd, La, Y). For the first time, the standard formation enthalpies of these phases have been determined as follows: ΔfH° (Bi12.5La1.5ReO24.5, s, 298.15 K) = −5659.7 ± 8.8 kJ/mol; ΔfH° (Bi12.5Nd1.5ReO24.5, s, 298.15 K) = −5702.6 ± 9.0 kJ/mol; ΔfH° (Bi12.5Y1.5ReO24.5, s, 298.15 K) = −5727.6 ± 8.8 kJ/mol. The thermodynamic stability at room temperature has been assessed. The results show that investigated phases are thermodynamically stable with respect to binary oxides and stable with respect to interaction with H2O at ambient temperatures. Bi12.5Nd1.5ReO24.5 and Bi12.5Y1.5ReO24.5 are thermodynamically stable but Bi12.5La1.5ReO24.5 is thermodynamically unstable with respect to interaction with CO2.
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Bryzgalova A. N. et al. Formation enthalpies and thermodynamics of some reactions of the Bi12.5R1.5ReO24.5 (R=Y, Nd, La) compounds // Thermochimica Acta. 2011. Vol. 513. No. 1-2. pp. 124-127.
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Bryzgalova A. N., Matskevich N., Greaves C. J., Hervoches C. Formation enthalpies and thermodynamics of some reactions of the Bi12.5R1.5ReO24.5 (R=Y, Nd, La) compounds // Thermochimica Acta. 2011. Vol. 513. No. 1-2. pp. 124-127.
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TY - JOUR
DO - 10.1016/j.tca.2010.11.022
UR - https://doi.org/10.1016/j.tca.2010.11.022
TI - Formation enthalpies and thermodynamics of some reactions of the Bi12.5R1.5ReO24.5 (R=Y, Nd, La) compounds
T2 - Thermochimica Acta
AU - Bryzgalova, A N
AU - Matskevich, N.I.
AU - Greaves, Colin J.
AU - Hervoches, C.H.
PY - 2011
DA - 2011/01/01
PB - Elsevier
SP - 124-127
IS - 1-2
VL - 513
SN - 0040-6031
SN - 1872-762X
ER -
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@article{2011_Bryzgalova,
author = {A N Bryzgalova and N.I. Matskevich and Colin J. Greaves and C.H. Hervoches},
title = {Formation enthalpies and thermodynamics of some reactions of the Bi12.5R1.5ReO24.5 (R=Y, Nd, La) compounds},
journal = {Thermochimica Acta},
year = {2011},
volume = {513},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.tca.2010.11.022},
number = {1-2},
pages = {124--127},
doi = {10.1016/j.tca.2010.11.022}
}
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Bryzgalova, A. N., et al. “Formation enthalpies and thermodynamics of some reactions of the Bi12.5R1.5ReO24.5 (R=Y, Nd, La) compounds.” Thermochimica Acta, vol. 513, no. 1-2, Jan. 2011, pp. 124-127. https://doi.org/10.1016/j.tca.2010.11.022.