Thermochimica Acta, volume 614, pages 9-15

Influence of structural factors on the thermal stability of zinc(II) and boron(III) complexes with iodo- and bromosubstituted 2,2′-dipyrrines

Publication typeJournal Article
Publication date2015-08-01
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor3.5
ISSN00406031, 1872762X
Physical and Theoretical Chemistry
Condensed Matter Physics
Instrumentation
Abstract
The results of the analysis of thermal stability for zinc (II) and boron (III) complexes with 3,3′,5,5′-tetramethyl-4-ethyl-4′-iodo-2,2-dipyrrin [HL1], 3,3′-diamyl-4,4′-dimethyl-5,5′-dibromo-2,2′-dipyrrin [HL2] and 3,3′,5,5′-tetramethyl-4,4′-dibromo-2,2′-dipyrrin [HL3] of the composition [Zn(L1)2]–[Zn(L3)2] and [BF2L1]–[BF2L3] are presented. The influence of halogenation of dipyrrin ligand is manifested in decreasing thermal stability of [Zn(L)2] and [BF2L] when replacing 4,4′-dibromosubstituted dipyrrin on 5,5′-dibromo- or 4-monoiodosubstituted ligand. Intramolecular red-ox-reactions with participation of halogen atoms are the main cause of thermal stability lowering of dipyrrinates [Zn(L)2] and [BF2L] compared with alkylsubstituted analogs. The obtained results are interesting for the development of laser dyes and sensors for PDT.

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Guseva G. B., Antinа E. V., Nuraneeva E. N. Influence of structural factors on the thermal stability of zinc(II) and boron(III) complexes with iodo- and bromosubstituted 2,2′-dipyrrines // Thermochimica Acta. 2015. Vol. 614. pp. 9-15.
GOST all authors (up to 50) Copy
Guseva G. B., Antinа E. V., Nuraneeva E. N. Influence of structural factors on the thermal stability of zinc(II) and boron(III) complexes with iodo- and bromosubstituted 2,2′-dipyrrines // Thermochimica Acta. 2015. Vol. 614. pp. 9-15.
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TY - JOUR
DO - 10.1016/j.tca.2015.05.028
UR - https://doi.org/10.1016%2Fj.tca.2015.05.028
TI - Influence of structural factors on the thermal stability of zinc(II) and boron(III) complexes with iodo- and bromosubstituted 2,2′-dipyrrines
T2 - Thermochimica Acta
AU - Antinа, E V
AU - Guseva, Galina B
AU - Nuraneeva, Ekaterina N
PY - 2015
DA - 2015/08/01 00:00:00
PB - Elsevier
SP - 9-15
VL - 614
SN - 0040-6031
SN - 1872-762X
ER -
BibTex
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BibTex Copy
@article{2015_Guseva,
author = {E V Antinа and Galina B Guseva and Ekaterina N Nuraneeva},
title = {Influence of structural factors on the thermal stability of zinc(II) and boron(III) complexes with iodo- and bromosubstituted 2,2′-dipyrrines},
journal = {Thermochimica Acta},
year = {2015},
volume = {614},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016%2Fj.tca.2015.05.028},
pages = {9--15},
doi = {10.1016/j.tca.2015.05.028}
}
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