том 615 страницы 68-71

Enthalpy of formation of (In, Gd)-doped barium cerate

Тип публикацииJournal Article
Дата публикации2015-09-01
scimago Q2
wos Q2
БС2
SJR0.64
CiteScore6.2
Impact factor3.5
ISSN00406031, 1872762X
Physical and Theoretical Chemistry
Condensed Matter Physics
Instrumentation
Краткое описание
Solution enthalpies of barium cerate doped by gadolinium and indium and a mixture of BaCl2 + 0.7CeCl3 + 2GdCl3 + 0.1InCl3 have been measured in 1 mol dm−3 HCl with 0.1 mol dm−3 KI. For the first time the standard molar formation enthalpy of BaCe0.7Gd0.2In0.1O2.85 has been determined by solution calorimetry as follows: ΔfH° (298.15 K) = −1615.84 ± 9.01 kJ mol−1. The stabilization energy for above-mentioned compound has been calculated as well. It has been shown that barium cerate doped gadolinium and indium has higher stabilization energy than BaCe0.7Nd0.2In0.1O2.85 and BaCeO3. The reaction enthalpy with CO2 interaction has been calculated for BaCe0.7Gd0.2In0.1O2.85.
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Matskevich N. et al. Enthalpy of formation of (In, Gd)-doped barium cerate // Thermochimica Acta. 2015. Vol. 615. pp. 68-71.
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Matskevich N., WOLF T., Adelmann P., Semerikova A. N., Anyfrieva O. I. Enthalpy of formation of (In, Gd)-doped barium cerate // Thermochimica Acta. 2015. Vol. 615. pp. 68-71.
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TY - JOUR
DO - 10.1016/j.tca.2015.07.012
UR - https://doi.org/10.1016/j.tca.2015.07.012
TI - Enthalpy of formation of (In, Gd)-doped barium cerate
T2 - Thermochimica Acta
AU - Matskevich, N.I.
AU - WOLF, Th.
AU - Adelmann, P.
AU - Semerikova, Anna N
AU - Anyfrieva, O I
PY - 2015
DA - 2015/09/01
PB - Elsevier
SP - 68-71
VL - 615
SN - 0040-6031
SN - 1872-762X
ER -
BibTex
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@article{2015_Matskevich,
author = {N.I. Matskevich and Th. WOLF and P. Adelmann and Anna N Semerikova and O I Anyfrieva},
title = {Enthalpy of formation of (In, Gd)-doped barium cerate},
journal = {Thermochimica Acta},
year = {2015},
volume = {615},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.tca.2015.07.012},
pages = {68--71},
doi = {10.1016/j.tca.2015.07.012}
}