Synthesis of functionalized benzothiophenes and dibenzothiophenes by twofold Heck and subsequent 6π-electrocyclization reactions of 2,3-dibromothiophenes and 2,3-dibromobenzothiophenes
Serge Mitherand Tengho Toguem
1
,
Malik Imran
2, 3
,
Munawar Hussain
1
,
Jamshed Iqbal
4
,
Alexander Villinger
1
,
Peter Langer
5
2
4
Тип публикации: Journal Article
Дата публикации: 2013-01-01
scimago Q3
wos Q2
БС2
SJR: 0.426
CiteScore: 4.1
Impact factor: 2.2
ISSN: 00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Краткое описание
Benzothiophenes and dibenzothiophenes were prepared by twofold Heck reactions of 2,3-dibromothiophene and 2,3-dibromobenzothiophene, respectively, and subsequent thermal 6π-electrocyclization. The Heck reaction of 2,3-dibromothiophene and 2,3-dibromobenzothiophene with 1 equiv of alkenes proceeded with different regioselectivities and afforded 2-alkenylthiophenes and 3-alkenylbenzothiophenes.
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Tengho Toguem S. M. et al. Synthesis of functionalized benzothiophenes and dibenzothiophenes by twofold Heck and subsequent 6π-electrocyclization reactions of 2,3-dibromothiophenes and 2,3-dibromobenzothiophenes // Tetrahedron. 2013. Vol. 69. No. 1. pp. 160-173.
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Tengho Toguem S. M., Imran M., Hussain M., Iqbal J., Villinger A., Langer P. Synthesis of functionalized benzothiophenes and dibenzothiophenes by twofold Heck and subsequent 6π-electrocyclization reactions of 2,3-dibromothiophenes and 2,3-dibromobenzothiophenes // Tetrahedron. 2013. Vol. 69. No. 1. pp. 160-173.
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TY - JOUR
DO - 10.1016/j.tet.2012.10.050
UR - https://doi.org/10.1016/j.tet.2012.10.050
TI - Synthesis of functionalized benzothiophenes and dibenzothiophenes by twofold Heck and subsequent 6π-electrocyclization reactions of 2,3-dibromothiophenes and 2,3-dibromobenzothiophenes
T2 - Tetrahedron
AU - Tengho Toguem, Serge Mitherand
AU - Imran, Malik
AU - Hussain, Munawar
AU - Iqbal, Jamshed
AU - Villinger, Alexander
AU - Langer, Peter
PY - 2013
DA - 2013/01/01
PB - Elsevier
SP - 160-173
IS - 1
VL - 69
SN - 0040-4020
SN - 1464-5416
ER -
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@article{2013_Tengho Toguem,
author = {Serge Mitherand Tengho Toguem and Malik Imran and Munawar Hussain and Jamshed Iqbal and Alexander Villinger and Peter Langer},
title = {Synthesis of functionalized benzothiophenes and dibenzothiophenes by twofold Heck and subsequent 6π-electrocyclization reactions of 2,3-dibromothiophenes and 2,3-dibromobenzothiophenes},
journal = {Tetrahedron},
year = {2013},
volume = {69},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.tet.2012.10.050},
number = {1},
pages = {160--173},
doi = {10.1016/j.tet.2012.10.050}
}
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MLA
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Tengho Toguem, Serge Mitherand, et al. “Synthesis of functionalized benzothiophenes and dibenzothiophenes by twofold Heck and subsequent 6π-electrocyclization reactions of 2,3-dibromothiophenes and 2,3-dibromobenzothiophenes.” Tetrahedron, vol. 69, no. 1, Jan. 2013, pp. 160-173. https://doi.org/10.1016/j.tet.2012.10.050.