Synthesis of arylated anthraquinones by site-selective Suzuki–Miyaura reactions of the bis(triflates) of 1,3-di(hydroxy)anthraquinones
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Albert-Einstein-Str. 29a 18059 Rostock Germany
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Publication type: Journal Article
Publication date: 2013-10-01
scimago Q3
wos Q2
SJR: 0.426
CiteScore: 4.1
Impact factor: 2.2
ISSN: 00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
Arylated anthraquinones were prepared by Suzuki–Miyaura reactions of the bis(triflates) of various 1,3-(dihydroxy)anthraquinones. While the reactions of the bis(triflates) of parent 1,3-(dihydroxy)anthraquinone and of 2-chloro-1,3-di(hydroxy)anthraquinone proceeded with very good site-selectivity, the corresponding reactions of the bis(triflate) of 2-fluoro-1,3-diarylanthraquinones were not site-selective, which was explained based on the π-donating effect of the fluorine atom.
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Total citations:
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Citations from 2024:
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(12.5%)
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Akrawi O. A. et al. Synthesis of arylated anthraquinones by site-selective Suzuki–Miyaura reactions of the bis(triflates) of 1,3-di(hydroxy)anthraquinones // Tetrahedron. 2013. Vol. 69. No. 43. pp. 9013-9024.
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Akrawi O. A., Khan A., Patonay T., Villinger A., Langer P. Synthesis of arylated anthraquinones by site-selective Suzuki–Miyaura reactions of the bis(triflates) of 1,3-di(hydroxy)anthraquinones // Tetrahedron. 2013. Vol. 69. No. 43. pp. 9013-9024.
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TY - JOUR
DO - 10.1016/j.tet.2013.08.041
UR - https://doi.org/10.1016/j.tet.2013.08.041
TI - Synthesis of arylated anthraquinones by site-selective Suzuki–Miyaura reactions of the bis(triflates) of 1,3-di(hydroxy)anthraquinones
T2 - Tetrahedron
AU - Akrawi, Omer A
AU - Khan, Afsar
AU - Patonay, Tamás
AU - Villinger, Alexander
AU - Langer, Peter
PY - 2013
DA - 2013/10/01
PB - Elsevier
SP - 9013-9024
IS - 43
VL - 69
SN - 0040-4020
SN - 1464-5416
ER -
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BibTex (up to 50 authors)
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@article{2013_Akrawi,
author = {Omer A Akrawi and Afsar Khan and Tamás Patonay and Alexander Villinger and Peter Langer},
title = {Synthesis of arylated anthraquinones by site-selective Suzuki–Miyaura reactions of the bis(triflates) of 1,3-di(hydroxy)anthraquinones},
journal = {Tetrahedron},
year = {2013},
volume = {69},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.tet.2013.08.041},
number = {43},
pages = {9013--9024},
doi = {10.1016/j.tet.2013.08.041}
}
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MLA
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Akrawi, Omer A., et al. “Synthesis of arylated anthraquinones by site-selective Suzuki–Miyaura reactions of the bis(triflates) of 1,3-di(hydroxy)anthraquinones.” Tetrahedron, vol. 69, no. 43, Oct. 2013, pp. 9013-9024. https://doi.org/10.1016/j.tet.2013.08.041.