Regiospecific synthesis of gem-dinitro derivatives of 2-halogenocycloalka[b]pyridine-3,4-dicarbonitriles
Publication type: Journal Article
Publication date: 2015-09-01
scimago Q3
wos Q2
SJR: 0.426
CiteScore: 4.1
Impact factor: 2.2
ISSN: 00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
A simple method for the synthesis of inaccessible gem-dinitro derivatives of pyridine is described. A wide range of 2-halogencycloalka[b]pyridine-3,4-dicarbonitriles are produced by the three-component reaction (ketone, TCNE, hydrohalic acid), side-chain nitration of latter with 60% nitric acid in a solvent-free conditions leads to the formation of gem-dinitro derivatives with high selectivity and without disturbing of other reaction centers.
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28
Total citations:
28
Citations from 2024:
2
(7%)
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GOST
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Ершов О. et al. Regiospecific synthesis of gem-dinitro derivatives of 2-halogenocycloalka[b]pyridine-3,4-dicarbonitriles // Tetrahedron. 2015. Vol. 71. No. 39. pp. 7445-7450.
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Ершов О., Maksimova V. N., Lipin K. V., Belikov M. Yu., Ievlev M. Y., Тафеенко В. А., Nasakin O. E. Regiospecific synthesis of gem-dinitro derivatives of 2-halogenocycloalka[b]pyridine-3,4-dicarbonitriles // Tetrahedron. 2015. Vol. 71. No. 39. pp. 7445-7450.
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RIS
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TY - JOUR
DO - 10.1016/j.tet.2015.06.031
UR - https://doi.org/10.1016/j.tet.2015.06.031
TI - Regiospecific synthesis of gem-dinitro derivatives of 2-halogenocycloalka[b]pyridine-3,4-dicarbonitriles
T2 - Tetrahedron
AU - Ершов, О.В.
AU - Maksimova, Veronika N
AU - Lipin, Konstanin V
AU - Belikov, Mikhail Yu
AU - Ievlev, Mikhail Yu.
AU - Тафеенко, В. А.
AU - Nasakin, Oleg E
PY - 2015
DA - 2015/09/01
PB - Elsevier
SP - 7445-7450
IS - 39
VL - 71
SN - 0040-4020
SN - 1464-5416
ER -
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BibTex (up to 50 authors)
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@article{2015_Ершов,
author = {О.В. Ершов and Veronika N Maksimova and Konstanin V Lipin and Mikhail Yu Belikov and Mikhail Yu. Ievlev and В. А. Тафеенко and Oleg E Nasakin},
title = {Regiospecific synthesis of gem-dinitro derivatives of 2-halogenocycloalka[b]pyridine-3,4-dicarbonitriles},
journal = {Tetrahedron},
year = {2015},
volume = {71},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.tet.2015.06.031},
number = {39},
pages = {7445--7450},
doi = {10.1016/j.tet.2015.06.031}
}
Cite this
MLA
Copy
Ершов, О.В., et al. “Regiospecific synthesis of gem-dinitro derivatives of 2-halogenocycloalka[b]pyridine-3,4-dicarbonitriles.” Tetrahedron, vol. 71, no. 39, Sep. 2015, pp. 7445-7450. https://doi.org/10.1016/j.tet.2015.06.031.
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