A modified Cu(0)-Cu(I)-mediated Caryl-Caryl Ullmann coupling for the synthesis of biaryls
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Program in Chemical Biology, Chulabhorn Graduate Institute, 54 Kamphaeng Phet 6 Road, Laksi, Bangkok 10210, Thailand
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Publication type: Journal Article
Publication date: 2016-10-01
scimago Q3
wos Q2
SJR: 0.426
CiteScore: 4.1
Impact factor: 2.2
ISSN: 00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
A novel Cu(0)-Cu(I)-mediated Caryl-Caryl Ullmann coupling has been successfully developed. The use of Cu(I) salts allowed the reactions to proceed under relatively mild conditions (65 °C in DMSO for 15–72 h). The developed method was compatible with a relatively wide range of functional groups simultaneously present on the aromatic ring of different electronic nature. The aryl halides with an electron-withdrawing group ortho to the halide or an electron-donating group meta or para to the halide furnished the corresponding products in good to excellent yields (up to 98%).
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Total citations:
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Citations from 2024:
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Yasamut K. et al. A modified Cu(0)-Cu(I)-mediated Caryl-Caryl Ullmann coupling for the synthesis of biaryls // Tetrahedron. 2016. Vol. 72. No. 40. pp. 5994-6000.
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Yasamut K., Jongcharoenkamol J., Ruchirawat S., Ploypradith P. A modified Cu(0)-Cu(I)-mediated Caryl-Caryl Ullmann coupling for the synthesis of biaryls // Tetrahedron. 2016. Vol. 72. No. 40. pp. 5994-6000.
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TY - JOUR
DO - 10.1016/j.tet.2016.07.063
UR - https://doi.org/10.1016/j.tet.2016.07.063
TI - A modified Cu(0)-Cu(I)-mediated Caryl-Caryl Ullmann coupling for the synthesis of biaryls
T2 - Tetrahedron
AU - Yasamut, Kittisak
AU - Jongcharoenkamol, Jira
AU - Ruchirawat, Somsak
AU - Ploypradith, Poonsakdi
PY - 2016
DA - 2016/10/01
PB - Elsevier
SP - 5994-6000
IS - 40
VL - 72
SN - 0040-4020
SN - 1464-5416
ER -
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@article{2016_Yasamut,
author = {Kittisak Yasamut and Jira Jongcharoenkamol and Somsak Ruchirawat and Poonsakdi Ploypradith},
title = {A modified Cu(0)-Cu(I)-mediated Caryl-Caryl Ullmann coupling for the synthesis of biaryls},
journal = {Tetrahedron},
year = {2016},
volume = {72},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.tet.2016.07.063},
number = {40},
pages = {5994--6000},
doi = {10.1016/j.tet.2016.07.063}
}
Cite this
MLA
Copy
Yasamut, Kittisak, et al. “A modified Cu(0)-Cu(I)-mediated Caryl-Caryl Ullmann coupling for the synthesis of biaryls.” Tetrahedron, vol. 72, no. 40, Oct. 2016, pp. 5994-6000. https://doi.org/10.1016/j.tet.2016.07.063.