Tetrahedron, volume 76, issue 51, pages 131153
Remote trifluoromethylthiolation of alcohols under visible light
1
Normandie Univ. INSA Rouen UNIROUEN CNRS COBRA (UMR 6014) 76000 Rouen France
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2
UMR6014 COBRA, 1 rue Tesniere 76821, Mont Saint Aignan, France
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Publication type: Journal Article
Publication date: 2020-12-01
Journal:
Tetrahedron
Quartile SCImago
Q2
Quartile WOS
Q3
Impact factor: 2.1
ISSN: 00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
An unprecedented remote and regioselective trifluoromethylthiolation reaction of alcohols was developed. Under mild conditions, a panel of free-alcohols was selectively functionalized with TolSO 2 SCF 3 reagent as the SCF 3 source in the presence of hypervalent iodide (PIDA) under blue light irradiation. This approach offered an operationally simple tool for the construction of a challenging C(sp 3 )-SCF 3 bond at the δ-position of an alcohol by C(sp 3 )-H bond functionalization. Initial mechanistic studies suggested a radical pathway.
Top-30
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Advanced Synthesis and Catalysis
2 publications, 22.22%
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European Journal of Organic Chemistry
1 publication, 11.11%
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Chemical Reviews
1 publication, 11.11%
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Journal of Organic Chemistry
1 publication, 11.11%
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Organic and Biomolecular Chemistry
1 publication, 11.11%
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Green Chemistry
1 publication, 11.11%
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1 publication, 11.11%
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Russian Chemical Reviews
1 publication, 11.11%
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1
2
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Citations by publishers
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1
2
3
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Wiley
3 publications, 33.33%
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American Chemical Society (ACS)
2 publications, 22.22%
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Royal Society of Chemistry (RSC)
2 publications, 22.22%
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Thieme
1 publication, 11.11%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 11.11%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Barday M. et al. Remote trifluoromethylthiolation of alcohols under visible light // Tetrahedron. 2020. Vol. 76. No. 51. p. 131153.
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Barday M., Blieck R., Ruyet L., Besset T. Remote trifluoromethylthiolation of alcohols under visible light // Tetrahedron. 2020. Vol. 76. No. 51. p. 131153.
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TY - JOUR
DO - 10.1016/j.tet.2020.131153
UR - https://doi.org/10.1016/j.tet.2020.131153
TI - Remote trifluoromethylthiolation of alcohols under visible light
T2 - Tetrahedron
AU - Barday, Manuel
AU - Blieck, Rémi
AU - Ruyet, Louise
AU - Besset, Tatiana
PY - 2020
DA - 2020/12/01 00:00:00
PB - Elsevier
SP - 131153
IS - 51
VL - 76
SN - 0040-4020
SN - 1464-5416
ER -
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@article{2020_Barday,
author = {Manuel Barday and Rémi Blieck and Louise Ruyet and Tatiana Besset},
title = {Remote trifluoromethylthiolation of alcohols under visible light},
journal = {Tetrahedron},
year = {2020},
volume = {76},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.tet.2020.131153},
number = {51},
pages = {131153},
doi = {10.1016/j.tet.2020.131153}
}
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Barday, Manuel, et al. “Remote trifluoromethylthiolation of alcohols under visible light.” Tetrahedron, vol. 76, no. 51, Dec. 2020, p. 131153. https://doi.org/10.1016/j.tet.2020.131153.