Synthesis of phosphorylated sulfoximines and sulfinamides and their application as ligands in asymmetric metal catalysis
Publication type: Journal Article
Publication date: 2011-02-01
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Starting from inexpensive materials and following simple protocols various N-phosphorylated sulfoximines and sulfinamides have been synthesized. The newly prepared compounds were then applied as chiral ligands in asymmetric transition metal catalysis. Phosphorus triamide-type ligands derived from (S)-glutamic acid were found to be the most efficient stereoselectors in enantioselective palladium-catalyzed allylic substitutions (up to 97% ee). On the other hand, diamidophosphite-type structures stemming from (S)-proline were the best ligands in rhodium-catalyzed hydrogenation reactions (up to 84% ee).
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GOST
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Benetskiy E. B., Bolm C. Synthesis of phosphorylated sulfoximines and sulfinamides and their application as ligands in asymmetric metal catalysis // Tetrahedron Asymmetry. 2011. Vol. 22. No. 3. pp. 373-378.
GOST all authors (up to 50)
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Benetskiy E. B., Bolm C. Synthesis of phosphorylated sulfoximines and sulfinamides and their application as ligands in asymmetric metal catalysis // Tetrahedron Asymmetry. 2011. Vol. 22. No. 3. pp. 373-378.
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RIS
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TY - JOUR
DO - 10.1016/j.tetasy.2011.02.005
UR - https://doi.org/10.1016/j.tetasy.2011.02.005
TI - Synthesis of phosphorylated sulfoximines and sulfinamides and their application as ligands in asymmetric metal catalysis
T2 - Tetrahedron Asymmetry
AU - Benetskiy, Eduard B
AU - Bolm, Carsten
PY - 2011
DA - 2011/02/01
PB - Elsevier
SP - 373-378
IS - 3
VL - 22
SN - 0957-4166
SN - 1362-511X
ER -
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BibTex (up to 50 authors)
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@article{2011_Benetskiy,
author = {Eduard B Benetskiy and Carsten Bolm},
title = {Synthesis of phosphorylated sulfoximines and sulfinamides and their application as ligands in asymmetric metal catalysis},
journal = {Tetrahedron Asymmetry},
year = {2011},
volume = {22},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.tetasy.2011.02.005},
number = {3},
pages = {373--378},
doi = {10.1016/j.tetasy.2011.02.005}
}
Cite this
MLA
Copy
Benetskiy, Eduard B., and Carsten Bolm. “Synthesis of phosphorylated sulfoximines and sulfinamides and their application as ligands in asymmetric metal catalysis.” Tetrahedron Asymmetry, vol. 22, no. 3, Feb. 2011, pp. 373-378. https://doi.org/10.1016/j.tetasy.2011.02.005.