volume 48 issue 36 pages 6360-6363

Regiochemistry of addition of aminoheterocycles to α-cyanocinnamonitriles: formation of aza-bridged bi- and tricycles

M. Wendt 1
Aaron Kunzer 1
Rodger F. Henry 2
Jeffrey Cross 2
Thomas G Pagano 2
1
 
Cancer Research, Global Pharmaceutical R&D, Abbott Laboratories, 100 Abbott Park Road, Abbott Park, IL 60064-6101, United States
2
 
Advanced Technology, Global Pharmaceutical R&D, Abbott Laboratories, 100 Abbott Park Road, Abbott Park, IL 60064-6101, United States
Publication typeJournal Article
Publication date2007-09-01
scimago Q3
wos Q3
SJR0.334
CiteScore3.2
Impact factor1.5
ISSN00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
The additions of various five-membered ring aminoheterocycles to α-cyanocinnamonitriles were studied. Regiochemistry of product formation can in most cases be controlled by choosing the appropriate electrophile. An α-cyanocinnamonitrile with an additional β-leaving group normally provides products arising from initial attack of the ring amino group, while exo attack predominates in the case of the parent α-cyanocinnamonitrile. Aminopyrazole and aminoindazole provide only exo products with either electrophile. Product assignments were made via X-ray and 2D NMR methods; these assignments serve as a benchmark to several literature references and to future investigations of conjugate additions of these nucleophiles.
Found 
Found 

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GOST Copy
Wendt M. et al. Regiochemistry of addition of aminoheterocycles to α-cyanocinnamonitriles: formation of aza-bridged bi- and tricycles // Tetrahedron Letters. 2007. Vol. 48. No. 36. pp. 6360-6363.
GOST all authors (up to 50) Copy
Wendt M., Kunzer A., Henry R. F., Cross J., Pagano T. G. Regiochemistry of addition of aminoheterocycles to α-cyanocinnamonitriles: formation of aza-bridged bi- and tricycles // Tetrahedron Letters. 2007. Vol. 48. No. 36. pp. 6360-6363.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.tetlet.2007.07.039
UR - https://doi.org/10.1016/j.tetlet.2007.07.039
TI - Regiochemistry of addition of aminoheterocycles to α-cyanocinnamonitriles: formation of aza-bridged bi- and tricycles
T2 - Tetrahedron Letters
AU - Wendt, M.
AU - Kunzer, Aaron
AU - Henry, Rodger F.
AU - Cross, Jeffrey
AU - Pagano, Thomas G
PY - 2007
DA - 2007/09/01
PB - Elsevier
SP - 6360-6363
IS - 36
VL - 48
SN - 0040-4039
SN - 1873-3581
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2007_Wendt,
author = {M. Wendt and Aaron Kunzer and Rodger F. Henry and Jeffrey Cross and Thomas G Pagano},
title = {Regiochemistry of addition of aminoheterocycles to α-cyanocinnamonitriles: formation of aza-bridged bi- and tricycles},
journal = {Tetrahedron Letters},
year = {2007},
volume = {48},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.tetlet.2007.07.039},
number = {36},
pages = {6360--6363},
doi = {10.1016/j.tetlet.2007.07.039}
}
MLA
Cite this
MLA Copy
Wendt, M., et al. “Regiochemistry of addition of aminoheterocycles to α-cyanocinnamonitriles: formation of aza-bridged bi- and tricycles.” Tetrahedron Letters, vol. 48, no. 36, Sep. 2007, pp. 6360-6363. https://doi.org/10.1016/j.tetlet.2007.07.039.