Tetrahedron Letters, volume 52, issue 10, pages 1136-1139
Olefin cyclopropanation with aryl diazocompounds upon catalysis by a dirhodium(II) complex
Publication type: Journal Article
Publication date: 2011-03-01
Journal:
Tetrahedron Letters
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.8
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
A dirhodium(II) complex with N-perfluorooctylsulfonylprolinate ligands is found to catalyze the cyclopropanation of olefins with simple aryl diazomethanes. In contrast to previously reported dirhodium(II) catalysts, the present complex works well not only with very electron-rich olefins such as enol ethers, but also with styrenes. Consequently, the present catalyst allows to prepare functionalized diarylcyclopropanes in moderate yields with good diastereoselectivity for the cis product, whereas the enantioselectivity of the reaction appears negligible.
Top-30
Citations by journals
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2
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Russian Chemical Reviews
2 publications, 11.76%
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Organic Letters
2 publications, 11.76%
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ACS Catalysis
2 publications, 11.76%
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Biochemical Pharmacology
1 publication, 5.88%
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ChemCatChem
1 publication, 5.88%
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Chirality
1 publication, 5.88%
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ChemInform
1 publication, 5.88%
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Journal of the American Chemical Society
1 publication, 5.88%
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Dalton Transactions
1 publication, 5.88%
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New Journal of Chemistry
1 publication, 5.88%
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Chemical Society Reviews
1 publication, 5.88%
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Organic Reaction Mechanisms
1 publication, 5.88%
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1
2
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Citations by publishers
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1
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3
4
5
6
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Wiley
6 publications, 35.29%
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American Chemical Society (ACS)
5 publications, 29.41%
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Royal Society of Chemistry (RSC)
3 publications, 17.65%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
2 publications, 11.76%
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Elsevier
1 publication, 5.88%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Verdecchia M., Tubaro C., Biffis A. Olefin cyclopropanation with aryl diazocompounds upon catalysis by a dirhodium(II) complex // Tetrahedron Letters. 2011. Vol. 52. No. 10. pp. 1136-1139.
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Verdecchia M., Tubaro C., Biffis A. Olefin cyclopropanation with aryl diazocompounds upon catalysis by a dirhodium(II) complex // Tetrahedron Letters. 2011. Vol. 52. No. 10. pp. 1136-1139.
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TY - JOUR
DO - 10.1016/j.tetlet.2011.01.002
UR - https://doi.org/10.1016/j.tetlet.2011.01.002
TI - Olefin cyclopropanation with aryl diazocompounds upon catalysis by a dirhodium(II) complex
T2 - Tetrahedron Letters
AU - Verdecchia, Mirella
AU - Tubaro, Cristina
AU - Biffis, Andrea
PY - 2011
DA - 2011/03/01 00:00:00
PB - Elsevier
SP - 1136-1139
IS - 10
VL - 52
SN - 0040-4039
SN - 1873-3581
ER -
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@article{2011_Verdecchia,
author = {Mirella Verdecchia and Cristina Tubaro and Andrea Biffis},
title = {Olefin cyclopropanation with aryl diazocompounds upon catalysis by a dirhodium(II) complex},
journal = {Tetrahedron Letters},
year = {2011},
volume = {52},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.tetlet.2011.01.002},
number = {10},
pages = {1136--1139},
doi = {10.1016/j.tetlet.2011.01.002}
}
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Verdecchia, Mirella, et al. “Olefin cyclopropanation with aryl diazocompounds upon catalysis by a dirhodium(II) complex.” Tetrahedron Letters, vol. 52, no. 10, Mar. 2011, pp. 1136-1139. https://doi.org/10.1016/j.tetlet.2011.01.002.