Reductive alkylation of bis(triflyl)methane through self-promoting formation of easily isolable 1,1-bis(triflyl)alkenes
Publication type: Journal Article
Publication date: 2013-04-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
A convenient and practical synthesis of 1,1-bis(triflyl)alkenes via self-promoting condensation of Tf2CH2 and aldehydes was developed and chemical behavior of these alkenes was investigated. Among the alkenes, easily isolable 1,1-bis(triflyl)alkadienes derived from α,β-unsaturated aldehydes could be used as useful building blocks for 1,1-bis(triflyl)alkanes. The 1,1-bis(triflyl)alkane thus obtained showed catalyst activity in the acetal forming reaction, which is a typical reaction catalyzed by Bronsted acids.
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Yanai H., EGAWA S., TAGUCHI T. Reductive alkylation of bis(triflyl)methane through self-promoting formation of easily isolable 1,1-bis(triflyl)alkenes // Tetrahedron Letters. 2013. Vol. 54. No. 17. pp. 2160-2163.
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Yanai H., EGAWA S., TAGUCHI T. Reductive alkylation of bis(triflyl)methane through self-promoting formation of easily isolable 1,1-bis(triflyl)alkenes // Tetrahedron Letters. 2013. Vol. 54. No. 17. pp. 2160-2163.
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RIS
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TY - JOUR
DO - 10.1016/j.tetlet.2013.02.039
UR - https://doi.org/10.1016/j.tetlet.2013.02.039
TI - Reductive alkylation of bis(triflyl)methane through self-promoting formation of easily isolable 1,1-bis(triflyl)alkenes
T2 - Tetrahedron Letters
AU - Yanai, Hikaru
AU - EGAWA, Saki
AU - TAGUCHI, TAKEO
PY - 2013
DA - 2013/04/01
PB - Elsevier
SP - 2160-2163
IS - 17
VL - 54
SN - 0040-4039
SN - 1873-3581
ER -
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BibTex (up to 50 authors)
Copy
@article{2013_Yanai,
author = {Hikaru Yanai and Saki EGAWA and TAKEO TAGUCHI},
title = {Reductive alkylation of bis(triflyl)methane through self-promoting formation of easily isolable 1,1-bis(triflyl)alkenes},
journal = {Tetrahedron Letters},
year = {2013},
volume = {54},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.tetlet.2013.02.039},
number = {17},
pages = {2160--2163},
doi = {10.1016/j.tetlet.2013.02.039}
}
Cite this
MLA
Copy
Yanai, Hikaru, et al. “Reductive alkylation of bis(triflyl)methane through self-promoting formation of easily isolable 1,1-bis(triflyl)alkenes.” Tetrahedron Letters, vol. 54, no. 17, Apr. 2013, pp. 2160-2163. https://doi.org/10.1016/j.tetlet.2013.02.039.