A N-heterocyclic carbene Ni(II) complex bearing bis(cyclopentadienyl) ligands as a precatalyst for the dehydrogenative silylation of alcohols with hydrosilanes
Publication type: Journal Article
Publication date: 2015-05-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
An air- and moisture-stable N -heterocyclic carbene Ni(II) complex bearing bis(cyclopentadienyl) ligands was found to be an effective precatalyst for the dehydrogenative silylation of alcohols with hydrosilanes. Various aryl and alkyl alcohols were silylated in the presence of the Ni catalyst (1–4 mol %) in toluene at 110 °C, giving the corresponding silyl ethers in 59–99% isolated yields. Time-course studies revealed that the reaction has an induction period, during which the Ni(II) complex would be reduced to catalytically active Ni(0) species.
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Total citations:
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Citations from 2025:
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(4.76%)
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Ohta H. et al. A N-heterocyclic carbene Ni(II) complex bearing bis(cyclopentadienyl) ligands as a precatalyst for the dehydrogenative silylation of alcohols with hydrosilanes // Tetrahedron Letters. 2015. Vol. 56. No. 22. pp. 2910-2912.
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Ohta H., Miyoshi N., SAKATA Y., Okamoto Y., Hayashi M., Watanabe Y. A N-heterocyclic carbene Ni(II) complex bearing bis(cyclopentadienyl) ligands as a precatalyst for the dehydrogenative silylation of alcohols with hydrosilanes // Tetrahedron Letters. 2015. Vol. 56. No. 22. pp. 2910-2912.
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RIS
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TY - JOUR
DO - 10.1016/j.tetlet.2015.04.069
UR - https://doi.org/10.1016/j.tetlet.2015.04.069
TI - A N-heterocyclic carbene Ni(II) complex bearing bis(cyclopentadienyl) ligands as a precatalyst for the dehydrogenative silylation of alcohols with hydrosilanes
T2 - Tetrahedron Letters
AU - Ohta, Hidetoshi
AU - Miyoshi, Narumi
AU - SAKATA, Yoshihiro
AU - Okamoto, Yuki
AU - Hayashi, Minoru
AU - Watanabe, Yutaka
PY - 2015
DA - 2015/05/01
PB - Elsevier
SP - 2910-2912
IS - 22
VL - 56
SN - 0040-4039
SN - 1873-3581
ER -
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BibTex (up to 50 authors)
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@article{2015_Ohta,
author = {Hidetoshi Ohta and Narumi Miyoshi and Yoshihiro SAKATA and Yuki Okamoto and Minoru Hayashi and Yutaka Watanabe},
title = {A N-heterocyclic carbene Ni(II) complex bearing bis(cyclopentadienyl) ligands as a precatalyst for the dehydrogenative silylation of alcohols with hydrosilanes},
journal = {Tetrahedron Letters},
year = {2015},
volume = {56},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/j.tetlet.2015.04.069},
number = {22},
pages = {2910--2912},
doi = {10.1016/j.tetlet.2015.04.069}
}
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MLA
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Ohta, Hidetoshi, et al. “A N-heterocyclic carbene Ni(II) complex bearing bis(cyclopentadienyl) ligands as a precatalyst for the dehydrogenative silylation of alcohols with hydrosilanes.” Tetrahedron Letters, vol. 56, no. 22, May. 2015, pp. 2910-2912. https://doi.org/10.1016/j.tetlet.2015.04.069.