Tetrahedron Letters

, volume 56 , issue 33 , pages 4775-4779

A metal-free approach for transamidation of amides with amines in aqueous media

Mahesuni Srinivas ^{1, 2}

Abhinandan D Hudwekar ^{1, 2}

Vunnam Venkateswarlu ^{1, 2}

G Lakshma Reddy ^{1, 2}

K A Aravinda Kumar ³

Ram Vishwakarma ^{1, 2}

Sanghapal D. Sawant ^{1, 2}

Hide authors affiliations Show authors affiliations: 3 affiliations

Academy of Scientific and Innovative Research, Anusandhan Bhawan, 2 Rafi Marg,New Delhi-110 001,India |

Medicinal Chemistry Division, CSIR-Indian Institute of Integrative Medicine, Canal Road,Jammu-180 001,India |

Medicinal Chemistry Division, CSIR-Indian Institute of Integrative Medicine, Canal Road,Jammu 180 001,India |

Publication type: Journal Article

Publication date: 2015-08-01

Elsevier

Tetrahedron Letters

scimago Q3

wos Q3

SJR: 0.334

CiteScore: 3.2

Impact factor: 1.5

ISSN: 00404039, 18733581

DOI: 10.1016/j.tetlet.2015.06.052

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Organic Chemistry

Drug Discovery

Biochemistry

Abstract

An efficient, environmentally benign and a mild protocol for transamidation of amides with a variety of amines in the presence of K2S2O8 using stoichiometric quantity in aqueous conditions has been established. This method works under conventional thermal conditions and in microwave irradiation as well. A series of amides have been prepared using this reaction and this is a greener protocol for transamidation, which offers a diverse kind of substrate scope with exclusive product formation (yields 90–98%).

Found

1 citation

Budnikova Yulia

DSc in Chemistry, professor

259 publications, 4 500 citations, 54 reviews

h-index: 34

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Research interests

C-H functionalization

Catalysis

Charge transfer

Chemistry of organoelement compounds

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GOST |

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GOST Copy

Srinivas M. et al. A metal-free approach for transamidation of amides with amines in aqueous media // Tetrahedron Letters. 2015. Vol. 56. No. 33. pp. 4775-4779.

GOST all authors (up to 50) Copy

Srinivas M., Hudwekar A. D., Venkateswarlu V., Reddy G. L., Kumar K. A. A., Vishwakarma R., Sawant S. D. A metal-free approach for transamidation of amides with amines in aqueous media // Tetrahedron Letters. 2015. Vol. 56. No. 33. pp. 4775-4779.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.tetlet.2015.06.052

UR - https://doi.org/10.1016/j.tetlet.2015.06.052

TI - A metal-free approach for transamidation of amides with amines in aqueous media

T2 - Tetrahedron Letters

AU - Srinivas, Mahesuni

AU - Hudwekar, Abhinandan D

AU - Venkateswarlu, Vunnam

AU - Reddy, G Lakshma

AU - Kumar, K A Aravinda

AU - Vishwakarma, Ram

AU - Sawant, Sanghapal D.

PY - 2015

DA - 2015/08/01

PB - Elsevier

SP - 4775-4779

IS - 33

VL - 56

SN - 0040-4039

SN - 1873-3581

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2015_Srinivas,

author = {Mahesuni Srinivas and Abhinandan D Hudwekar and Vunnam Venkateswarlu and G Lakshma Reddy and K A Aravinda Kumar and Ram Vishwakarma and Sanghapal D. Sawant},

title = {A metal-free approach for transamidation of amides with amines in aqueous media},

journal = {Tetrahedron Letters},

year = {2015},

volume = {56},

publisher = {Elsevier},

month = {aug},

url = {https://doi.org/10.1016/j.tetlet.2015.06.052},

number = {33},

pages = {4775--4779},

doi = {10.1016/j.tetlet.2015.06.052}

}

MLA

Cite this

MLA Copy

Srinivas, Mahesuni, et al. “A metal-free approach for transamidation of amides with amines in aqueous media.” Tetrahedron Letters, vol. 56, no. 33, Aug. 2015, pp. 4775-4779. https://doi.org/10.1016/j.tetlet.2015.06.052.

Publisher

Elsevier

Journal

Tetrahedron Letters

scimago Q3

wos Q3

SJR

0.334

CiteScore

3.2

Impact factor

1.5

ISSN

00404039 (Print)

18733581 (Electronic)