One-pot tandem hydrophenylation and ionic hydrogenation of 3-phenylpropynoic acid derivatives under superelectrophilic activation
Publication type: Journal Article
Publication date: 2015-10-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
The reactions of esters and amides of 3-phenylpropynoic acid with strong Lewis acids AlX 3 (X = Cl, Br) or conjugate Bronsted–Lewis superacids HX-AlX 3 (X = Cl, Br) in benzene and cyclohexane at room temperature afforded 3,3-diphenylpropanoic acid derivatives in up to 94% yield. This tandem reaction of the acetylene bond proceeded by hydrophenylation followed by ionic hydrogenation.
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Nilov D. I., Vasilyev A. V. One-pot tandem hydrophenylation and ionic hydrogenation of 3-phenylpropynoic acid derivatives under superelectrophilic activation // Tetrahedron Letters. 2015. Vol. 56. No. 42. pp. 5714-5717.
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Nilov D. I., Vasilyev A. V. One-pot tandem hydrophenylation and ionic hydrogenation of 3-phenylpropynoic acid derivatives under superelectrophilic activation // Tetrahedron Letters. 2015. Vol. 56. No. 42. pp. 5714-5717.
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RIS
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TY - JOUR
DO - 10.1016/j.tetlet.2015.09.026
UR - https://doi.org/10.1016/j.tetlet.2015.09.026
TI - One-pot tandem hydrophenylation and ionic hydrogenation of 3-phenylpropynoic acid derivatives under superelectrophilic activation
T2 - Tetrahedron Letters
AU - Nilov, Denis I
AU - Vasilyev, Aleksander V
PY - 2015
DA - 2015/10/01
PB - Elsevier
SP - 5714-5717
IS - 42
VL - 56
SN - 0040-4039
SN - 1873-3581
ER -
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BibTex (up to 50 authors)
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@article{2015_Nilov,
author = {Denis I Nilov and Aleksander V Vasilyev},
title = {One-pot tandem hydrophenylation and ionic hydrogenation of 3-phenylpropynoic acid derivatives under superelectrophilic activation},
journal = {Tetrahedron Letters},
year = {2015},
volume = {56},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.tetlet.2015.09.026},
number = {42},
pages = {5714--5717},
doi = {10.1016/j.tetlet.2015.09.026}
}
Cite this
MLA
Copy
Nilov, Denis I., and Aleksander V Vasilyev. “One-pot tandem hydrophenylation and ionic hydrogenation of 3-phenylpropynoic acid derivatives under superelectrophilic activation.” Tetrahedron Letters, vol. 56, no. 42, Oct. 2015, pp. 5714-5717. https://doi.org/10.1016/j.tetlet.2015.09.026.