Unusual transformations of 7-imino-6-oxabicyclo[3.2.1]oct-3-ene-1,8,8-tricarbonitriles in acidic media
Publication type: Journal Article
Publication date: 2017-08-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
The transformations of 7-imino-6-oxabicyclo[3.2.1]oct-3-ene-1,8,8-tricarbonitrile derivatives in various hydrochloric acid media were studied. It was found that, depending on the reaction conditions, either hydrolysis of the imino group and isolation of the corresponding 7-oxo-6-oxabicyclo[3.2.1]oct-3-ene-1,8,8-tricarbonitriles occured or a cascade transformation takes place to form 2-chloro-1,6,6-tricyanocyclohex-3-ene-1-carboxamides.
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Ievlev M. Y. et al. Unusual transformations of 7-imino-6-oxabicyclo[3.2.1]oct-3-ene-1,8,8-tricarbonitriles in acidic media // Tetrahedron Letters. 2017. Vol. 58. No. 32. pp. 3148-3150.
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Ievlev M. Y., Ершов О., Lipin K. V., Belikov M. Yu., Тафеенко В. А. Unusual transformations of 7-imino-6-oxabicyclo[3.2.1]oct-3-ene-1,8,8-tricarbonitriles in acidic media // Tetrahedron Letters. 2017. Vol. 58. No. 32. pp. 3148-3150.
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TY - JOUR
DO - 10.1016/j.tetlet.2017.06.090
UR - https://doi.org/10.1016/j.tetlet.2017.06.090
TI - Unusual transformations of 7-imino-6-oxabicyclo[3.2.1]oct-3-ene-1,8,8-tricarbonitriles in acidic media
T2 - Tetrahedron Letters
AU - Ievlev, Mikhail Yu.
AU - Ершов, О.В.
AU - Lipin, K V
AU - Belikov, Mikhail Yu
AU - Тафеенко, В. А.
PY - 2017
DA - 2017/08/01
PB - Elsevier
SP - 3148-3150
IS - 32
VL - 58
SN - 0040-4039
SN - 1873-3581
ER -
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@article{2017_Ievlev,
author = {Mikhail Yu. Ievlev and О.В. Ершов and K V Lipin and Mikhail Yu Belikov and В. А. Тафеенко},
title = {Unusual transformations of 7-imino-6-oxabicyclo[3.2.1]oct-3-ene-1,8,8-tricarbonitriles in acidic media},
journal = {Tetrahedron Letters},
year = {2017},
volume = {58},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/j.tetlet.2017.06.090},
number = {32},
pages = {3148--3150},
doi = {10.1016/j.tetlet.2017.06.090}
}
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MLA
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Ievlev, Mikhail Yu., et al. “Unusual transformations of 7-imino-6-oxabicyclo[3.2.1]oct-3-ene-1,8,8-tricarbonitriles in acidic media.” Tetrahedron Letters, vol. 58, no. 32, Aug. 2017, pp. 3148-3150. https://doi.org/10.1016/j.tetlet.2017.06.090.
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