volume 59 issue 8 pages 723-726

PCl 3 - and organometallic-free synthesis of tris(2-picolyl)phosphine oxide from elemental phosphorus and 2-(chloromethyl)pyridine hydrochloride

Publication typeJournal Article
Publication date2018-02-01
scimago Q3
wos Q3
SJR0.334
CiteScore3.2
Impact factor1.5
ISSN00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
In the superbase KOH/H2O/toluene/phase-transfer catalyst system, 2-picolyl chloride, generated in situ from 2-(chloromethyl)pyridine hydrochloride, reacts with elemental phosphorus at 65–95 °C for 3 h to afford tris(2-picolyl)phosphine oxide in 50% yield. Single crystal X-ray analysis of the latter revealed one polymorph form of this tertiary phosphine oxide.
Found 
Found 

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GOST Copy
Malysheva S. A. et al. PCl 3 - and organometallic-free synthesis of tris(2-picolyl)phosphine oxide from elemental phosphorus and 2-(chloromethyl)pyridine hydrochloride // Tetrahedron Letters. 2018. Vol. 59. No. 8. pp. 723-726.
GOST all authors (up to 50) Copy
Malysheva S. A., Belogorlova N. A., Kuimov V. A., Litvintsev Y. I., Sterkhova I., Albanov A. I., Gusarova N. K., Trofimov B. A. PCl 3 - and organometallic-free synthesis of tris(2-picolyl)phosphine oxide from elemental phosphorus and 2-(chloromethyl)pyridine hydrochloride // Tetrahedron Letters. 2018. Vol. 59. No. 8. pp. 723-726.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.tetlet.2018.01.021
UR - https://doi.org/10.1016/j.tetlet.2018.01.021
TI - PCl 3 - and organometallic-free synthesis of tris(2-picolyl)phosphine oxide from elemental phosphorus and 2-(chloromethyl)pyridine hydrochloride
T2 - Tetrahedron Letters
AU - Malysheva, Svetlana A.
AU - Belogorlova, Nataliya A.
AU - Kuimov, Vladimir A
AU - Litvintsev, Yurii I
AU - Sterkhova, Irina
AU - Albanov, Alexander I
AU - Gusarova, Nina K.
AU - Trofimov, B. A.
PY - 2018
DA - 2018/02/01
PB - Elsevier
SP - 723-726
IS - 8
VL - 59
SN - 0040-4039
SN - 1873-3581
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Malysheva,
author = {Svetlana A. Malysheva and Nataliya A. Belogorlova and Vladimir A Kuimov and Yurii I Litvintsev and Irina Sterkhova and Alexander I Albanov and Nina K. Gusarova and B. A. Trofimov},
title = {PCl 3 - and organometallic-free synthesis of tris(2-picolyl)phosphine oxide from elemental phosphorus and 2-(chloromethyl)pyridine hydrochloride},
journal = {Tetrahedron Letters},
year = {2018},
volume = {59},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.tetlet.2018.01.021},
number = {8},
pages = {723--726},
doi = {10.1016/j.tetlet.2018.01.021}
}
MLA
Cite this
MLA Copy
Malysheva, Svetlana A., et al. “PCl 3 - and organometallic-free synthesis of tris(2-picolyl)phosphine oxide from elemental phosphorus and 2-(chloromethyl)pyridine hydrochloride.” Tetrahedron Letters, vol. 59, no. 8, Feb. 2018, pp. 723-726. https://doi.org/10.1016/j.tetlet.2018.01.021.