Rh(III)-catalyzed synthesis of isoquinolines using the N-Cl bond of N-chloroimines as an internal oxidant
Publication type: Journal Article
Publication date: 2020-04-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
The Rh(III)-catalyzed coupling of N-chloroimines with alkynes for the efficient synthesis of isoquinolines is reported. This represents the first use of the N-Cl bond of N-chloroimines as an internal oxidant for construction of the isoquinoline skeleton. The synthesis features atom and step economy, a green solvent (EtOH), mild reaction conditions, and a broad substrate scope.
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13
Total citations:
13
Citations from 2025:
2
(15.38%)
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GOST
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QI B. et al. Rh(III)-catalyzed synthesis of isoquinolines using the N-Cl bond of N-chloroimines as an internal oxidant // Tetrahedron Letters. 2020. Vol. 61. No. 16. p. 151771.
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QI B., Fang L., Wang Q., Guo S., Shi P., Chu B., Zhu J. Rh(III)-catalyzed synthesis of isoquinolines using the N-Cl bond of N-chloroimines as an internal oxidant // Tetrahedron Letters. 2020. Vol. 61. No. 16. p. 151771.
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RIS
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TY - JOUR
DO - 10.1016/j.tetlet.2020.151771
UR - https://doi.org/10.1016/j.tetlet.2020.151771
TI - Rh(III)-catalyzed synthesis of isoquinolines using the N-Cl bond of N-chloroimines as an internal oxidant
T2 - Tetrahedron Letters
AU - QI, BING
AU - Fang, Lili
AU - Wang, Qi
AU - Guo, Shan
AU - Shi, Pengfei
AU - Chu, Benfa
AU - Zhu, Jin
PY - 2020
DA - 2020/04/01
PB - Elsevier
SP - 151771
IS - 16
VL - 61
SN - 0040-4039
SN - 1873-3581
ER -
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BibTex (up to 50 authors)
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@article{2020_QI,
author = {BING QI and Lili Fang and Qi Wang and Shan Guo and Pengfei Shi and Benfa Chu and Jin Zhu},
title = {Rh(III)-catalyzed synthesis of isoquinolines using the N-Cl bond of N-chloroimines as an internal oxidant},
journal = {Tetrahedron Letters},
year = {2020},
volume = {61},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.tetlet.2020.151771},
number = {16},
pages = {151771},
doi = {10.1016/j.tetlet.2020.151771}
}
Cite this
MLA
Copy
QI, BING, et al. “Rh(III)-catalyzed synthesis of isoquinolines using the N-Cl bond of N-chloroimines as an internal oxidant.” Tetrahedron Letters, vol. 61, no. 16, Apr. 2020, p. 151771. https://doi.org/10.1016/j.tetlet.2020.151771.