Tetrahedron Letters, volume 61, issue 25, pages 151990
“Diels-Alder reaction” in the ionic version: GaCl3-promoted formation of substituted cyclohexenes from donor–acceptor cyclopropanes and dienes
Publication type: Journal Article
Publication date: 2020-06-01
Journal:
Tetrahedron Letters
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.8
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
A selective process of formal [2 + 4]-cycloaddition of donor–acceptor cyclopropanes (2-arylcyclopropane-1,1-dicarboxylates) in the presence of GaCl3 to conjugated dienes to give cyclohex-3-ene-1,1-dicarboxylates has been developed. This process occurs by generation of 1,2-zwitterionic gallium complexes and involves the addition of a carbocationic center to a terminal diene atom followed by 1,6-cyclization to the allyl position of the resulting intermediate.
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Citations by publishers
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American Chemical Society (ACS)
4 publications, 23.53%
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2 publications, 11.76%
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1 publication, 5.88%
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- We do not take into account publications without a DOI.
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- Statistics recalculated weekly.
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Belaya M. A. et al. “Diels-Alder reaction” in the ionic version: GaCl3-promoted formation of substituted cyclohexenes from donor–acceptor cyclopropanes and dienes // Tetrahedron Letters. 2020. Vol. 61. No. 25. p. 151990.
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Belaya M. A., Knyazev D. A., Novikov R. G., Tomilov Y. V., Tomilov Y. V. “Diels-Alder reaction” in the ionic version: GaCl3-promoted formation of substituted cyclohexenes from donor–acceptor cyclopropanes and dienes // Tetrahedron Letters. 2020. Vol. 61. No. 25. p. 151990.
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TY - JOUR
DO - 10.1016/j.tetlet.2020.151990
UR - https://doi.org/10.1016/j.tetlet.2020.151990
TI - “Diels-Alder reaction” in the ionic version: GaCl3-promoted formation of substituted cyclohexenes from donor–acceptor cyclopropanes and dienes
T2 - Tetrahedron Letters
AU - Belaya, Maria A
AU - Knyazev, Daniil A
AU - Novikov, Roman G.
AU - Tomilov, Yury V
AU - Tomilov, Yury V.
PY - 2020
DA - 2020/06/01 00:00:00
PB - Elsevier
SP - 151990
IS - 25
VL - 61
SN - 0040-4039
SN - 1873-3581
ER -
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@article{2020_Belaya,
author = {Maria A Belaya and Daniil A Knyazev and Roman G. Novikov and Yury V Tomilov and Yury V. Tomilov},
title = {“Diels-Alder reaction” in the ionic version: GaCl3-promoted formation of substituted cyclohexenes from donor–acceptor cyclopropanes and dienes},
journal = {Tetrahedron Letters},
year = {2020},
volume = {61},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.tetlet.2020.151990},
number = {25},
pages = {151990},
doi = {10.1016/j.tetlet.2020.151990}
}
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MLA
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Belaya, Maria A., et al. ““Diels-Alder reaction” in the ionic version: GaCl3-promoted formation of substituted cyclohexenes from donor–acceptor cyclopropanes and dienes.” Tetrahedron Letters, vol. 61, no. 25, Jun. 2020, p. 151990. https://doi.org/10.1016/j.tetlet.2020.151990.