Ligand-free copper-catalyzed direct amidation of diaryliodonium salts using nitriles as amidation reagents
Hui Cheng Cheng
1
,
Zhou Lichao
1
,
Xuming Zhou
1
,
Jiao Li Ma
1
,
Penghu Guo
1
,
Yang Zhang
1
,
Honglin Ji Honglin Ji
2
Publication type: Journal Article
Publication date: 2021-05-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
An efficient and practical methodology for the synthesis of N-arylamides has been developed via copper-catalyzed amidation of diaryliodonium salts with nitriles. Various substituted aryl nitriles and aliphatic nitriles could be applied in the reaction, providing a series of N-arylated amides in moderate to good yields. This procedure provides an alternative route for the synthesis of various N-arylamides. A proposed mechanism based on control experiments is also presented.
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9
Total citations:
9
Citations from 2024:
4
(44.44%)
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Cheng H. C. et al. Ligand-free copper-catalyzed direct amidation of diaryliodonium salts using nitriles as amidation reagents // Tetrahedron Letters. 2021. Vol. 71. p. 153048.
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Cheng H. C., Lichao Z., Zhou X., Ma J. L., Guo P., Zhang Y., Honglin Ji H. J. Ligand-free copper-catalyzed direct amidation of diaryliodonium salts using nitriles as amidation reagents // Tetrahedron Letters. 2021. Vol. 71. p. 153048.
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TY - JOUR
DO - 10.1016/j.tetlet.2021.153048
UR - https://doi.org/10.1016/j.tetlet.2021.153048
TI - Ligand-free copper-catalyzed direct amidation of diaryliodonium salts using nitriles as amidation reagents
T2 - Tetrahedron Letters
AU - Cheng, Hui Cheng
AU - Lichao, Zhou
AU - Zhou, Xuming
AU - Ma, Jiao Li
AU - Guo, Penghu
AU - Zhang, Yang
AU - Honglin Ji, Honglin Ji
PY - 2021
DA - 2021/05/01
PB - Elsevier
SP - 153048
VL - 71
SN - 0040-4039
SN - 1873-3581
ER -
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@article{2021_Cheng,
author = {Hui Cheng Cheng and Zhou Lichao and Xuming Zhou and Jiao Li Ma and Penghu Guo and Yang Zhang and Honglin Ji Honglin Ji},
title = {Ligand-free copper-catalyzed direct amidation of diaryliodonium salts using nitriles as amidation reagents},
journal = {Tetrahedron Letters},
year = {2021},
volume = {71},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/j.tetlet.2021.153048},
pages = {153048},
doi = {10.1016/j.tetlet.2021.153048}
}