Effect of solvent polarity on the aggregation of fullerenes: a comparison between C60 and C70
Publication type: Journal Article
Publication date: 2002-07-01
scimago Q2
wos Q2
SJR: 0.546
CiteScore: 5.9
Impact factor: 3.1
ISSN: 00092614, 18734448
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Effect of solvent polarity on the aggregation behaviour of C70 has been investigated in several mixed solvents using optical absorption, fluorescence, dynamic light scattering and scanning electron microscopic measurements and compared with those observed for the other fullerene analogue, C60. It is seen that similar to C60, aggregation of C70 also requires the solvent polarity to exceed some critical value. In terms of solvent dielectric constant the critical solvent polarity, required for C70 aggregation is found to be in the range of ∼27–31, which is much higher than that required for C60 aggregation (∼12–14). The large difference in the critical solvent polarity required for C60 and C70 aggregation has been rationalized on the basis of the molecular shapes and the polarizabilities of two fullerene molecules.
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NATH S., PAL H., Sapre A. V. Effect of solvent polarity on the aggregation of fullerenes: a comparison between C60 and C70 // Chemical Physics Letters. 2002. Vol. 360. No. 5-6. pp. 422-428.
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NATH S., PAL H., Sapre A. V. Effect of solvent polarity on the aggregation of fullerenes: a comparison between C60 and C70 // Chemical Physics Letters. 2002. Vol. 360. No. 5-6. pp. 422-428.
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TY - JOUR
DO - 10.1016/s0009-2614(02)00780-7
UR - https://doi.org/10.1016/s0009-2614(02)00780-7
TI - Effect of solvent polarity on the aggregation of fullerenes: a comparison between C60 and C70
T2 - Chemical Physics Letters
AU - NATH, S
AU - PAL, H
AU - Sapre, Avinash V.
PY - 2002
DA - 2002/07/01
PB - Elsevier
SP - 422-428
IS - 5-6
VL - 360
SN - 0009-2614
SN - 1873-4448
ER -
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BibTex (up to 50 authors)
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@article{2002_NATH,
author = {S NATH and H PAL and Avinash V. Sapre},
title = {Effect of solvent polarity on the aggregation of fullerenes: a comparison between C60 and C70},
journal = {Chemical Physics Letters},
year = {2002},
volume = {360},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/s0009-2614(02)00780-7},
number = {5-6},
pages = {422--428},
doi = {10.1016/s0009-2614(02)00780-7}
}
Cite this
MLA
Copy
NATH, S., et al. “Effect of solvent polarity on the aggregation of fullerenes: a comparison between C60 and C70.” Chemical Physics Letters, vol. 360, no. 5-6, Jul. 2002, pp. 422-428. https://doi.org/10.1016/s0009-2614(02)00780-7.