On the reduction behaviour of 2-methoxyethyl and 2-methylthioethyl substituted zirconocene dichlorides: Crystal structure of (η5,σ-C5 Me4 CH2 CH 2 S)2 Zr
Publication type: Journal Article
Publication date: 1998-10-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract A reduction of previously reported 2-methoxyethyl and 2-methylthioethyl functionalized zirconocenedichlorides (η5-C5Me4CH2CH2EMe)(η5-C5Me5)(ZrCl2 (E = O, S) and (η5-C5Me4CH2CH2EMe)(η5-C5Me4CH2CH2E′Me)ZrCl2 (E = O, S; E′ = O, S) with Mg/Hg in THF leads unexpectedly to the products of OMe and SMe bond cleavage (η5,σ-C5Me4CH2CH2E)(η5-C5Me5)ZrMe (E = O, S), (η5,σ-C5Me4CH2CH2E)(η5-C5Me4CH2CH2E′Me)ZrMe (E = O, S; E′ = O), and (η5,σ-C5Me4CH2CH2S)2Zr respectively. The crystal structure of (η5,σ-C5Me4CH2CH2S)2Zr was established by X-ray analysis. At that same time the reduction of (ηsu5-C5Me4CH2CH2EMe)(η5-C5Me5)ZrCl2 (E> = O, S) under 1 atm of CO gives either only the dicarbonyl derivative (η5-C5Me4CH2CH2EMe) (η5-C6Me5)Zr(CO)2 (E = O) or a complex mixture of products (E = S).
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
|
|
|
Russian Chemical Bulletin
4 publications, 22.22%
|
|
|
Journal of Organometallic Chemistry
3 publications, 16.67%
|
|
|
Organometallics
3 publications, 16.67%
|
|
|
Coordination Chemistry Reviews
2 publications, 11.11%
|
|
|
Chemical Reviews
2 publications, 11.11%
|
|
|
Inorganic Chemistry Communication
1 publication, 5.56%
|
|
|
New Journal of Chemistry
1 publication, 5.56%
|
|
|
1
2
3
4
|
Publishers
|
1
2
3
4
5
6
7
8
|
|
|
Elsevier
8 publications, 44.44%
|
|
|
American Chemical Society (ACS)
5 publications, 27.78%
|
|
|
Springer Nature
4 publications, 22.22%
|
|
|
Royal Society of Chemistry (RSC)
1 publication, 5.56%
|
|
|
1
2
3
4
5
6
7
8
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
18
Total citations:
18
Citations from 2024:
0
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Krutko D. P. et al. On the reduction behaviour of 2-methoxyethyl and 2-methylthioethyl substituted zirconocene dichlorides: Crystal structure of (η5,σ-C5Me4CH2CH 2S)2Zr // Inorganica Chimica Acta. 1998. Vol. 280. No. 1-2. pp. 257-263.
GOST all authors (up to 50)
Copy
Krutko D. P., Borzov M. V., Kuz'mina L. G., Churakov A. V., Lemenovskii D. A., Reutov O. A. On the reduction behaviour of 2-methoxyethyl and 2-methylthioethyl substituted zirconocene dichlorides: Crystal structure of (η5,σ-C5Me4CH2CH 2S)2Zr // Inorganica Chimica Acta. 1998. Vol. 280. No. 1-2. pp. 257-263.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/s0020-1693(98)00175-3
UR - https://linkinghub.elsevier.com/retrieve/pii/S0020169398001753
TI - On the reduction behaviour of 2-methoxyethyl and 2-methylthioethyl substituted zirconocene dichlorides: Crystal structure of (η5,σ-C5Me4CH2CH 2S)2Zr
T2 - Inorganica Chimica Acta
AU - Krutko, D P
AU - Borzov, M V
AU - Kuz'mina, L. G.
AU - Churakov, Andrei V.
AU - Lemenovskii, D A
AU - Reutov, O A
PY - 1998
DA - 1998/10/01
PB - Elsevier
SP - 257-263
IS - 1-2
VL - 280
SN - 0020-1693
SN - 1873-3255
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1998_Krutko,
author = {D P Krutko and M V Borzov and L. G. Kuz'mina and Andrei V. Churakov and D A Lemenovskii and O A Reutov},
title = {On the reduction behaviour of 2-methoxyethyl and 2-methylthioethyl substituted zirconocene dichlorides: Crystal structure of (η5,σ-C5Me4CH2CH 2S)2Zr},
journal = {Inorganica Chimica Acta},
year = {1998},
volume = {280},
publisher = {Elsevier},
month = {oct},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0020169398001753},
number = {1-2},
pages = {257--263},
doi = {10.1016/s0020-1693(98)00175-3}
}
Cite this
MLA
Copy
Krutko, D. P., et al. “On the reduction behaviour of 2-methoxyethyl and 2-methylthioethyl substituted zirconocene dichlorides: Crystal structure of (η5,σ-C5Me4CH2CH 2S)2Zr.” Inorganica Chimica Acta, vol. 280, no. 1-2, Oct. 1998, pp. 257-263. https://linkinghub.elsevier.com/retrieve/pii/S0020169398001753.