Syntheses and lipophilicities of tetraarylborate ions substituted with many trifluoromethyl groups
Publication type: Journal Article
Publication date: 1992-04-01
scimago Q3
wos Q3
SJR: 0.333
CiteScore: 3.7
Impact factor: 1.9
ISSN: 00221139, 18733328
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Environmental Chemistry
Abstract
Syntheses were investigated using various tetraarylborate ions with a large number of trifluoromethyl groups: tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; tetrakis [3,5-bis(1-methoxy-2,2,2-trifluoro-1-(trifluoromethyl)ethyl) phenyl] borate; tetrakis[3-(1- methoxy-2,2,2-trifluoro-1-(trifluoromethyl)ethyl)-5-(trifluoromethyl)phenyl] borate; and tetrakis[3-(2,2,2- trifluoro-1-(2,2,2-trifluoroethyoxy)-1-(trifluoromethyl)ethyl)-5- (trifluoromethyl)phenyl]borate ions. The preparation of Grignard reagents and the subsequent reaction with boron trifluoride etherate are important steps for a higher yield and easier isolation of the product. Sodium- and tetramethylammonium salts of these borate ions are soluble in halocarbon solvents such as dichloromethane, chloroform and 1,2-dibromotetrafluoroethane.
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Total citations:
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Citations from 2025:
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GOST
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Fujiki K. et al. Syntheses and lipophilicities of tetraarylborate ions substituted with many trifluoromethyl groups // Journal of Fluorine Chemistry. 1992. Vol. 57. No. 1-3. pp. 307-321.
GOST all authors (up to 50)
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Fujiki K., Kashiwagi M., MIYAMOTO H., Sonoda A., Ichikawa J., Kobayashi H., SONODA T. Syntheses and lipophilicities of tetraarylborate ions substituted with many trifluoromethyl groups // Journal of Fluorine Chemistry. 1992. Vol. 57. No. 1-3. pp. 307-321.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/s0022-1139(00)82842-0
UR - https://doi.org/10.1016/s0022-1139(00)82842-0
TI - Syntheses and lipophilicities of tetraarylborate ions substituted with many trifluoromethyl groups
T2 - Journal of Fluorine Chemistry
AU - Fujiki, Kanji
AU - Kashiwagi, Mitsuyoshi
AU - MIYAMOTO, HIDEYUKI
AU - Sonoda, Akinari
AU - Ichikawa, J.
AU - Kobayashi, Hiroshi
AU - SONODA, Takaaki
PY - 1992
DA - 1992/04/01
PB - Elsevier
SP - 307-321
IS - 1-3
VL - 57
SN - 0022-1139
SN - 1873-3328
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1992_Fujiki,
author = {Kanji Fujiki and Mitsuyoshi Kashiwagi and HIDEYUKI MIYAMOTO and Akinari Sonoda and J. Ichikawa and Hiroshi Kobayashi and Takaaki SONODA},
title = {Syntheses and lipophilicities of tetraarylborate ions substituted with many trifluoromethyl groups},
journal = {Journal of Fluorine Chemistry},
year = {1992},
volume = {57},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/s0022-1139(00)82842-0},
number = {1-3},
pages = {307--321},
doi = {10.1016/s0022-1139(00)82842-0}
}
Cite this
MLA
Copy
Fujiki, Kanji, et al. “Syntheses and lipophilicities of tetraarylborate ions substituted with many trifluoromethyl groups.” Journal of Fluorine Chemistry, vol. 57, no. 1-3, Apr. 1992, pp. 307-321. https://doi.org/10.1016/s0022-1139(00)82842-0.