Modelling nucleophilic substitution at silicon using hypervalent silicon compounds based on urea ligands
1
The Chemistry Department, The Open University, Walton Hall, Milton Keynes, Buckinghamshire MK7 6AA, UK
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Publication type: Journal Article
Publication date: 2001-01-30
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The X-ray crystal structure of a pentacoordinate silicon compound, 3 , with a urea ligand shows partial Si–O bond formation and Si–Cl cleavage. The solution NMR parameters for the related series of compounds with different leaving groups provides structural information and this can be used to model substitution at silicon. The corresponding thioureas exhibit N–Si bond formation with the silicon remaining tetracoordinate.
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34
Total citations:
34
Citations from 2025:
1
(2.94%)
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GOST
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Bassindale A. Modelling nucleophilic substitution at silicon using hypervalent silicon compounds based on urea ligands // Journal of Organometallic Chemistry. 2001. Vol. 619. No. 1-2. pp. 132-140.
GOST all authors (up to 50)
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Bassindale A. Modelling nucleophilic substitution at silicon using hypervalent silicon compounds based on urea ligands // Journal of Organometallic Chemistry. 2001. Vol. 619. No. 1-2. pp. 132-140.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/s0022-328x(00)00562-3
UR - https://doi.org/10.1016/s0022-328x(00)00562-3
TI - Modelling nucleophilic substitution at silicon using hypervalent silicon compounds based on urea ligands
T2 - Journal of Organometallic Chemistry
AU - Bassindale, A
PY - 2001
DA - 2001/01/30
PB - Elsevier
SP - 132-140
IS - 1-2
VL - 619
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2001_Bassindale,
author = {A Bassindale},
title = {Modelling nucleophilic substitution at silicon using hypervalent silicon compounds based on urea ligands},
journal = {Journal of Organometallic Chemistry},
year = {2001},
volume = {619},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/s0022-328x(00)00562-3},
number = {1-2},
pages = {132--140},
doi = {10.1016/s0022-328x(00)00562-3}
}
Cite this
MLA
Copy
Bassindale, A.. “Modelling nucleophilic substitution at silicon using hypervalent silicon compounds based on urea ligands.” Journal of Organometallic Chemistry, vol. 619, no. 1-2, Jan. 2001, pp. 132-140. https://doi.org/10.1016/s0022-328x(00)00562-3.