Synthesis of two stereoisomeric polydentate ligands, trans and cis cyclopentane-1,2-diaminotetraacetic acids, and complexation by 111In and 153Sm
Sébastien G Gouin
1, 2
,
Jean-François Gestin
1
,
Kevin Joly
2
,
Anthony Loussouarn
3
,
Alain Reliquet
2
,
Jean Claude Meslin
2
,
David Deniaud
2
2
Laboratoire de Synthèse Organique, Faculté des Sciences et des Techniques, UMR CNRS 6513, 2, rue de la Houssinière, BP 92208, 44072 Nantes cedex, France
|
3
CHELATEC SAS, Institut de Biologie, 9, quai Moncousu, 44093 Nantes cedex, France
|
Тип публикации: Journal Article
Дата публикации: 2002-02-01
scimago Q3
wos Q2
БС2
SJR: 0.426
CiteScore: 4.1
Impact factor: 2.2
ISSN: 00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Краткое описание
Two polyaminocarboxylic acid chelating agents were synthesized. Complexation properties regarding 111In and 153Sm, two radionuclides suitable for applications in immunoscintigraphy and radioimmunotherapy were investigated. The synthesis of aminodiacetic acid derivatives 7a and 7b involved preliminary stereoselective synthesis of the corresponding amines, cis and trans cyclopentane-1,2-diamines. 111In labelling confirmed the complexation abilities of the two ligands. An additional comparative study to probe the relationship between ligand structure and metal complex was performed with 153Sm.
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Gouin S. G. et al. Synthesis of two stereoisomeric polydentate ligands, trans and cis cyclopentane-1,2-diaminotetraacetic acids, and complexation by 111In and 153Sm // Tetrahedron. 2002. Vol. 58. No. 6. pp. 1131-1136.
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Gouin S. G., Gestin J., Joly K., Loussouarn A., Reliquet A., Claude Meslin J., Deniaud D. Synthesis of two stereoisomeric polydentate ligands, trans and cis cyclopentane-1,2-diaminotetraacetic acids, and complexation by 111In and 153Sm // Tetrahedron. 2002. Vol. 58. No. 6. pp. 1131-1136.
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TY - JOUR
DO - 10.1016/s0040-4020(01)01198-x
UR - https://doi.org/10.1016/s0040-4020(01)01198-x
TI - Synthesis of two stereoisomeric polydentate ligands, trans and cis cyclopentane-1,2-diaminotetraacetic acids, and complexation by 111In and 153Sm
T2 - Tetrahedron
AU - Gouin, Sébastien G
AU - Gestin, Jean-François
AU - Joly, Kevin
AU - Loussouarn, Anthony
AU - Reliquet, Alain
AU - Claude Meslin, Jean
AU - Deniaud, David
PY - 2002
DA - 2002/02/01
PB - Elsevier
SP - 1131-1136
IS - 6
VL - 58
SN - 0040-4020
SN - 1464-5416
ER -
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@article{2002_Gouin,
author = {Sébastien G Gouin and Jean-François Gestin and Kevin Joly and Anthony Loussouarn and Alain Reliquet and Jean Claude Meslin and David Deniaud},
title = {Synthesis of two stereoisomeric polydentate ligands, trans and cis cyclopentane-1,2-diaminotetraacetic acids, and complexation by 111In and 153Sm},
journal = {Tetrahedron},
year = {2002},
volume = {58},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/s0040-4020(01)01198-x},
number = {6},
pages = {1131--1136},
doi = {10.1016/s0040-4020(01)01198-x}
}
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MLA
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Gouin, Sébastien G., et al. “Synthesis of two stereoisomeric polydentate ligands, trans and cis cyclopentane-1,2-diaminotetraacetic acids, and complexation by 111In and 153Sm.” Tetrahedron, vol. 58, no. 6, Feb. 2002, pp. 1131-1136. https://doi.org/10.1016/s0040-4020(01)01198-x.