Polyhedron, volume 18, issue 22, pages 2931-2939
Synthesis and anti-Candida activity of copper(II) and manganese(II) carboxylate complexes
1
Chemistry Dept., National University of Ireland Maynooth, Maynooth, Co. Kildare, Ireland
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2
Dublin Institute of Technology Cathal Brugha Street Dublin Ireland.
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Publication type: Journal Article
Publication date: 1999-09-01
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract The copper(II) complexes [Cu(salH)2(H2O)2]·0.5H2O (1) (salH2=salicylic acid) and [Cu2(asp)4]·3H2O (8) {aspH=acetylsalicylic acid (aspirin)} both react with imidazole (imid), 1,10-phenanthroline (phen) and 2,2′-bipyridine (bipy) giving [Cu(sal)(imid)] (2), [Cu(sal)(phen)] (3) and [Cu(sal)(bipy)]·C2H5OH·H2O (4). CuCl2·2H2O reacts with cis-5-norbornene-endo-2,3-dicarboxylic acid (norbH2) and NaOH giving [Cu(norb)]·H2O (9). Complexes 4 and 9 were crystallographically characterised. The above complexes, together with the related manganese(II) complexes, [Mn2(salH)4(H2O)4] (5), [Mn(salH)2(phen)] (6), [Mn(salH)2(bipy)]·H2O (7), [Mn(norb)H2O] (11) and [Mn(norb)(phen)2]·C2H5OH·H2O (12) and also the metal-free ligands were screened for their ability to inhibit the growth of the pathogenic yeast Candida albicans. 1,0-Phenanthroline and the phenanthroline complexes 6, 10b and 12 exhibited high anti-Candida activity with the manganese complexes 6 and 12 being the most potent.
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Geraghty M. et al. Synthesis and anti-Candida activity of copper(II) and manganese(II) carboxylate complexes // Polyhedron. 1999. Vol. 18. No. 22. pp. 2931-2939.
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Geraghty M., Sheridan V., McCann M., Devereux M., McKee V. Synthesis and anti-Candida activity of copper(II) and manganese(II) carboxylate complexes // Polyhedron. 1999. Vol. 18. No. 22. pp. 2931-2939.
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TY - JOUR
DO - 10.1016/S0277-5387(99)00201-6
UR - https://doi.org/10.1016/S0277-5387(99)00201-6
TI - Synthesis and anti-Candida activity of copper(II) and manganese(II) carboxylate complexes
T2 - Polyhedron
AU - Geraghty, Majella
AU - Sheridan, Vivienne
AU - McCann, Malachy
AU - Devereux, Michael
AU - McKee, Vickie
PY - 1999
DA - 1999/09/01 00:00:00
PB - Elsevier
SP - 2931-2939
IS - 22
VL - 18
SN - 0277-5387
ER -
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@article{1999_Geraghty,
author = {Majella Geraghty and Vivienne Sheridan and Malachy McCann and Michael Devereux and Vickie McKee},
title = {Synthesis and anti-Candida activity of copper(II) and manganese(II) carboxylate complexes},
journal = {Polyhedron},
year = {1999},
volume = {18},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/S0277-5387(99)00201-6},
number = {22},
pages = {2931--2939},
doi = {10.1016/S0277-5387(99)00201-6}
}
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Geraghty, Majella, et al. “Synthesis and anti-Candida activity of copper(II) and manganese(II) carboxylate complexes.” Polyhedron, vol. 18, no. 22, Sep. 1999, pp. 2931-2939. https://doi.org/10.1016/S0277-5387(99)00201-6.