Mechanism of Br2·− and Cl2·− radical anions formation upon IrCl62− photoreduction in methanol solutions containing free Br− and Cl− ions
E.M Glebov
1
,
Victor F. Plyusnin
1
,
Vjacheslav P. Grivin
1
,
Yu. V. Ivanov
1
,
Helge Lemmetyinen
2
1
Institute of Chemical Kinetics and Combustton, Novosibirsk 610090, Russian Federation
|
Тип публикации: Journal Article
Дата публикации: 1998-02-01
scimago Q2
wos Q2
БС1
SJR: 0.694
CiteScore: 7.8
Impact factor: 4.7
ISSN: 10106030, 18732666
General Chemistry
General Chemical Engineering
General Physics and Astronomy
Краткое описание
Laser flash photolysis has been used to study the formation of X 2 ·− radical ions (X = Br and Cl) upon photoreduction of IrCl 6 2− complex in methanol solutions, containing free X − ions. It has been shown that two channels of halogen atom formation are possible. These are the reactions Of X − ions with either the primary radical cation CH 3 OH ·+ which results from single electron transfer from a methanol molecule to the excited complex or the intermediate, arising from transformation of primary light-excited IrCl 6 2− complex.
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Glebov E. et al. Mechanism of Br2·− and Cl2·− radical anions formation upon IrCl62− photoreduction in methanol solutions containing free Br− and Cl− ions // Journal of Photochemistry and Photobiology A: Chemistry. 1998. Vol. 113. No. 2. pp. 103-112.
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Glebov E., Plyusnin V. F., Grivin V. P., Ivanov Y. V., Tkachenko N., Lemmetyinen H. Mechanism of Br2·− and Cl2·− radical anions formation upon IrCl62− photoreduction in methanol solutions containing free Br− and Cl− ions // Journal of Photochemistry and Photobiology A: Chemistry. 1998. Vol. 113. No. 2. pp. 103-112.
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TY - JOUR
DO - 10.1016/s1010-6030(97)00337-7
UR - https://doi.org/10.1016/s1010-6030(97)00337-7
TI - Mechanism of Br2·− and Cl2·− radical anions formation upon IrCl62− photoreduction in methanol solutions containing free Br− and Cl− ions
T2 - Journal of Photochemistry and Photobiology A: Chemistry
AU - Glebov, E.M
AU - Plyusnin, Victor F.
AU - Grivin, Vjacheslav P.
AU - Ivanov, Yu. V.
AU - Tkachenko, Nikolai
AU - Lemmetyinen, Helge
PY - 1998
DA - 1998/02/01
PB - Elsevier
SP - 103-112
IS - 2
VL - 113
SN - 1010-6030
SN - 1873-2666
ER -
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BibTex (до 50 авторов)
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@article{1998_Glebov,
author = {E.M Glebov and Victor F. Plyusnin and Vjacheslav P. Grivin and Yu. V. Ivanov and Nikolai Tkachenko and Helge Lemmetyinen},
title = {Mechanism of Br2·− and Cl2·− radical anions formation upon IrCl62− photoreduction in methanol solutions containing free Br− and Cl− ions},
journal = {Journal of Photochemistry and Photobiology A: Chemistry},
year = {1998},
volume = {113},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/s1010-6030(97)00337-7},
number = {2},
pages = {103--112},
doi = {10.1016/s1010-6030(97)00337-7}
}
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MLA
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Glebov, E.M, et al. “Mechanism of Br2·− and Cl2·− radical anions formation upon IrCl62− photoreduction in methanol solutions containing free Br− and Cl− ions.” Journal of Photochemistry and Photobiology A: Chemistry, vol. 113, no. 2, Feb. 1998, pp. 103-112. https://doi.org/10.1016/s1010-6030(97)00337-7.