(R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine: an N-aryl pyrrolidine ligand for enantioselective transfer hydrogenation
António Manuel d’Albuquerque Rocha Gonsalves
1
,
M.Elisa S Serra
1
,
Manuela Ramos Silva
2
,
Ana Matos Beja
2
,
J. A. Paixão
2
,
Luiz Alte da Veiga
2
Publication type: Journal Article
Publication date: 2001-03-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 13811169
Catalysis
Physical and Theoretical Chemistry
Process Chemistry and Technology
Abstract
The N-aryl pyrrolidine diphosphine (R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine was obtained from natural tartaric acid. Contrary to our preliminary expectations, this new chiral ligand proved to be less selective than the corresponding N-benzyl pyrrolidine diphosphine. An attempted explanation of the observed behaviour based on the stereochemistry of the ligand as shown by X-ray crystallography is presented.
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Total citations:
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GOST
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Gonsalves A. M. D. R. et al. (R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine: an N-aryl pyrrolidine ligand for enantioselective transfer hydrogenation // Journal of Molecular Catalysis A Chemical. 2001. Vol. 168. No. 1-2. pp. 53-59.
GOST all authors (up to 50)
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Gonsalves A. M. D. R., Serra M. S., Silva M. R., Beja A. M., Paixão J. A., Veiga L. A. D. (R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine: an N-aryl pyrrolidine ligand for enantioselective transfer hydrogenation // Journal of Molecular Catalysis A Chemical. 2001. Vol. 168. No. 1-2. pp. 53-59.
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RIS
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TY - JOUR
DO - 10.1016/s1381-1169(00)00531-8
UR - https://doi.org/10.1016/s1381-1169(00)00531-8
TI - (R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine: an N-aryl pyrrolidine ligand for enantioselective transfer hydrogenation
T2 - Journal of Molecular Catalysis A Chemical
AU - Gonsalves, António Manuel d’Albuquerque Rocha
AU - Serra, M.Elisa S
AU - Silva, Manuela Ramos
AU - Beja, Ana Matos
AU - Paixão, J. A.
AU - Veiga, Luiz Alte da
PY - 2001
DA - 2001/03/01
PB - Elsevier
SP - 53-59
IS - 1-2
VL - 168
SN - 1381-1169
ER -
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BibTex (up to 50 authors)
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@article{2001_Gonsalves,
author = {António Manuel d’Albuquerque Rocha Gonsalves and M.Elisa S Serra and Manuela Ramos Silva and Ana Matos Beja and J. A. Paixão and Luiz Alte da Veiga},
title = {(R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine: an N-aryl pyrrolidine ligand for enantioselective transfer hydrogenation},
journal = {Journal of Molecular Catalysis A Chemical},
year = {2001},
volume = {168},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/s1381-1169(00)00531-8},
number = {1-2},
pages = {53--59},
doi = {10.1016/s1381-1169(00)00531-8}
}
Cite this
MLA
Copy
Gonsalves, António Manuel d’Albuquerque Rocha, et al. “(R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine: an N-aryl pyrrolidine ligand for enantioselective transfer hydrogenation.” Journal of Molecular Catalysis A Chemical, vol. 168, no. 1-2, Mar. 2001, pp. 53-59. https://doi.org/10.1016/s1381-1169(00)00531-8.
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