Journal of Molecular Catalysis A Chemical

, том 168 , издание 1-2 , страницы 53-59

(R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine: an N-aryl pyrrolidine ligand for enantioselective transfer hydrogenation

António Manuel d’Albuquerque Rocha Gonsalves ¹

M.Elisa S Serra ¹

Manuela Ramos Silva ²

Ana Matos Beja ²

J. A. Paixão ²

Luiz Alte da Veiga ²

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Departamento de Quı́mica, Faculdade de Ciências e Tecnologia, Universidade de Coimbra, P-3000 Coimbra, Portugal |

Departamento de Fı́sica, FCTUC, Centro de Estudos de Materiais por Difracção de Raios-X, Universidade de Coimbra, P-3000 Coimbra, Portugal |

Тип публикации: Journal Article

Дата публикации: 2001-03-01

Elsevier

Journal of Molecular Catalysis A Chemical

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ISSN: 13811169

DOI: 10.1016/s1381-1169(00)00531-8

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Краткое описание

The N-aryl pyrrolidine diphosphine (R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine was obtained from natural tartaric acid. Contrary to our preliminary expectations, this new chiral ligand proved to be less selective than the corresponding N-benzyl pyrrolidine diphosphine. An attempted explanation of the observed behaviour based on the stereochemistry of the ligand as shown by X-ray crystallography is presented.

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Gonsalves A. M. D. R. et al. (R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine: an N-aryl pyrrolidine ligand for enantioselective transfer hydrogenation // Journal of Molecular Catalysis A Chemical. 2001. Vol. 168. No. 1-2. pp. 53-59.

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Gonsalves A. M. D. R., Serra M. S., Silva M. R., Beja A. M., Paixão J. A., Veiga L. A. D. (R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine: an N-aryl pyrrolidine ligand for enantioselective transfer hydrogenation // Journal of Molecular Catalysis A Chemical. 2001. Vol. 168. No. 1-2. pp. 53-59.

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TY - JOUR

DO - 10.1016/s1381-1169(00)00531-8

UR - https://doi.org/10.1016/s1381-1169(00)00531-8

TI - (R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine: an N-aryl pyrrolidine ligand for enantioselective transfer hydrogenation

T2 - Journal of Molecular Catalysis A Chemical

AU - Gonsalves, António Manuel d’Albuquerque Rocha

AU - Serra, M.Elisa S

AU - Silva, Manuela Ramos

AU - Beja, Ana Matos

AU - Paixão, J. A.

AU - Veiga, Luiz Alte da

PY - 2001

DA - 2001/03/01

PB - Elsevier

SP - 53-59

IS - 1-2

VL - 168

SN - 1381-1169

ER -

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@article{2001_Gonsalves,

author = {António Manuel d’Albuquerque Rocha Gonsalves and M.Elisa S Serra and Manuela Ramos Silva and Ana Matos Beja and J. A. Paixão and Luiz Alte da Veiga},

title = {(R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine: an N-aryl pyrrolidine ligand for enantioselective transfer hydrogenation},

journal = {Journal of Molecular Catalysis A Chemical},

year = {2001},

volume = {168},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016/s1381-1169(00)00531-8},

number = {1-2},

pages = {53--59},

doi = {10.1016/s1381-1169(00)00531-8}

}

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Gonsalves, António Manuel d’Albuquerque Rocha, et al. “(R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine: an N-aryl pyrrolidine ligand for enantioselective transfer hydrogenation.” Journal of Molecular Catalysis A Chemical, vol. 168, no. 1-2, Mar. 2001, pp. 53-59. https://doi.org/10.1016/s1381-1169(00)00531-8.

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Elsevier

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Journal of Molecular Catalysis A Chemical

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—

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—

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—

ISSN

13811169 (Print)

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