Crystal structure of tetrabutylammonium [bis(1,3-dithiole-2-thione-4,5-dithiolato)bismuthate(1-)], [NBu4][Bi(dmit)2]
Nadia Maria Comerlato
1
,
William William E. Harrison (2)
2
,
R. Alan Howie
2
,
Alexandre C. Silvino
1
,
James N. Wardell
1
,
Solange M. S. V. Wardell
2
Publication type: Journal Article
Publication date: 2000-11-01
scimago Q1
wos Q1
SJR: 0.758
CiteScore: 6.7
Impact factor: 5.4
ISSN: 13877003, 18790259
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The crystal structure of ionic [NBu4][Bi(dmit)2] (5: Q=NBu4), obtained from BiBr3 and [NBu4]2[Zn(dmit)2], has been determined. The bismuth atoms are six coordinate, as a consequence of two inter-anion Bi–S contacts with two neighbouring anions. In addition to the four intra-anion Bi—S bonds to the two thiolato S atoms of the dmit ligands [Bi–S between 2.5872(14) and 2.8082(13) A: the inter-anion bonds involve thione S atoms [Bi—S(10)i=3.2548(11) and Bi–S(10)ii 3.4628(13) A]. Excluding consideration of any lone pair effect, the Bi atoms have very distorted octahedral geometries. The anions form centrosymmetric pairs of chains with the shortest Bi–Bi distance of 4.180 A being between the pairs of chains; overlapping parallel dmit ligands, within the pairs of chains, are separated by a perpendicular distance of 3.477(2) A, with the dmit centroid–dmit centroid separation of 3.529 A, ideal for π–π interaction.
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Comerlato N. M. et al. Crystal structure of tetrabutylammonium [bis(1,3-dithiole-2-thione-4,5-dithiolato)bismuthate(1-)], [NBu4][Bi(dmit)2] // Inorganic Chemistry Communication. 2000. Vol. 3. No. 11. pp. 572-574.
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Comerlato N. M., William E. Harrison (2) W., Howie R. A., Silvino A. C., Wardell J. N., Wardell S. M. S. V. Crystal structure of tetrabutylammonium [bis(1,3-dithiole-2-thione-4,5-dithiolato)bismuthate(1-)], [NBu4][Bi(dmit)2] // Inorganic Chemistry Communication. 2000. Vol. 3. No. 11. pp. 572-574.
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TY - JOUR
DO - 10.1016/s1387-7003(00)00143-x
UR - https://doi.org/10.1016/s1387-7003(00)00143-x
TI - Crystal structure of tetrabutylammonium [bis(1,3-dithiole-2-thione-4,5-dithiolato)bismuthate(1-)], [NBu4][Bi(dmit)2]
T2 - Inorganic Chemistry Communication
AU - Comerlato, Nadia Maria
AU - William E. Harrison (2), William
AU - Howie, R. Alan
AU - Silvino, Alexandre C.
AU - Wardell, James N.
AU - Wardell, Solange M. S. V.
PY - 2000
DA - 2000/11/01
PB - Elsevier
SP - 572-574
IS - 11
VL - 3
SN - 1387-7003
SN - 1879-0259
ER -
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@article{2000_Comerlato,
author = {Nadia Maria Comerlato and William William E. Harrison (2) and R. Alan Howie and Alexandre C. Silvino and James N. Wardell and Solange M. S. V. Wardell},
title = {Crystal structure of tetrabutylammonium [bis(1,3-dithiole-2-thione-4,5-dithiolato)bismuthate(1-)], [NBu4][Bi(dmit)2]},
journal = {Inorganic Chemistry Communication},
year = {2000},
volume = {3},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/s1387-7003(00)00143-x},
number = {11},
pages = {572--574},
doi = {10.1016/s1387-7003(00)00143-x}
}
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MLA
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Comerlato, Nadia Maria, et al. “Crystal structure of tetrabutylammonium [bis(1,3-dithiole-2-thione-4,5-dithiolato)bismuthate(1-)], [NBu4][Bi(dmit)2].” Inorganic Chemistry Communication, vol. 3, no. 11, Nov. 2000, pp. 572-574. https://doi.org/10.1016/s1387-7003(00)00143-x.