Inorganic Chemistry, volume 60, issue 12, pages 8592-8604
Synthesis of Perchlorinated Sulfonium Derivatives of closo-Decaborate Anion [2-B10Cl9SR2]- (R = i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, n-C18H37, CH2Ph, and cyclo-S(CH2)4).
Publication type: Journal Article
Publication date: 2021-05-27
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A method for obtaining perchlorinated di-S,S-substituted derivatives of the closo-decaborate anion with various alkyl groups has been developed: [B10Cl9SR2]- (R= i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, n-C18H37, CH2Ph, and cyclo-S(CH2)4). The method is based on the preparation of the sulfonium-substituted anion [B10H9SR2]- by alkylation of the anion [B10H9SH]2- with bromoalkanes (i-C3H7Br, n-C3H7Br, n-C4H9Br, n-C8H17Br, n-C12H25Br, n-C18H37Br, PhCH2Br, and BrCH2(CH2)2CH2Br) followed by the cluster chlorination with sulfuryl chloride SO2Cl2 in acetonitrile. The process proceeds until the hydrogen atoms in the boron cluster are completely replaced with chlorine and completes within 60 h. It has been found that the melting point of salts ((C4H9)4N)[B10Cl9SR2] (R= i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, and n-C18H37) strongly depends on the length of the hydrocarbon chain of the substituent R.
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- We do not take into account publications that without a DOI.
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- Statistics recalculated weekly.
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Golubev A. E. et al. Synthesis of Perchlorinated Sulfonium Derivatives of closo-Decaborate Anion [2-B10Cl9SR2]- (R = i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, n-C18H37, CH2Ph, and cyclo-S(CH2)4). // Inorganic Chemistry. 2021. Vol. 60. No. 12. pp. 8592-8604.
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Golubev A. E., Kubasov A. S., Bykov A. Yu., Novikov A. S., Kravchenko E. A., Gippius A. A., Zhurenko S. V., Semenova V. A., Korlyukov A., Grigoriev M. S. Synthesis of Perchlorinated Sulfonium Derivatives of closo-Decaborate Anion [2-B10Cl9SR2]- (R = i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, n-C18H37, CH2Ph, and cyclo-S(CH2)4). // Inorganic Chemistry. 2021. Vol. 60. No. 12. pp. 8592-8604.
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TY - JOUR
DO - 10.1021/ACS.INORGCHEM.1C00516
UR - https://doi.org/10.1021%2FACS.INORGCHEM.1C00516
TI - Synthesis of Perchlorinated Sulfonium Derivatives of closo-Decaborate Anion [2-B10Cl9SR2]- (R = i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, n-C18H37, CH2Ph, and cyclo-S(CH2)4).
T2 - Inorganic Chemistry
AU - Kravchenko, Eleonora A
AU - Gippius, Andrei A
AU - Zhurenko, Sergey V
AU - Semenova, Veronica A
AU - Golubev, Aleksei E.
AU - Kubasov, Alexey S.
AU - Bykov, Alexander Yu
AU - Korlyukov, Alexander
AU - Novikov, Alexander S.
AU - Grigoriev, Mikhail S.
PY - 2021
DA - 2021/05/27 00:00:00
PB - American Chemical Society (ACS)
SP - 8592-8604
IS - 12
VL - 60
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2021_Golubev,
author = {Eleonora A Kravchenko and Andrei A Gippius and Sergey V Zhurenko and Veronica A Semenova and Aleksei E. Golubev and Alexey S. Kubasov and Alexander Yu Bykov and Alexander Korlyukov and Alexander S. Novikov and Mikhail S. Grigoriev},
title = {Synthesis of Perchlorinated Sulfonium Derivatives of closo-Decaborate Anion [2-B10Cl9SR2]- (R = i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, n-C18H37, CH2Ph, and cyclo-S(CH2)4).},
journal = {Inorganic Chemistry},
year = {2021},
volume = {60},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021%2FACS.INORGCHEM.1C00516},
number = {12},
pages = {8592--8604},
doi = {10.1021/ACS.INORGCHEM.1C00516}
}
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Golubev, Aleksei E., et al. “Synthesis of Perchlorinated Sulfonium Derivatives of closo-Decaborate Anion [2-B10Cl9SR2]- (R = i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, n-C18H37, CH2Ph, and cyclo-S(CH2)4)..” Inorganic Chemistry, vol. 60, no. 12, May. 2021, pp. 8592-8604. https://doi.org/10.1021%2FACS.INORGCHEM.1C00516.