Synthesis of Perchlorinated Sulfonium Derivatives of closo-Decaborate Anion [2-B10Cl9SR2]- (R = i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, n-C18H37, CH2Ph, and cyclo-S(CH2)4).
Тип публикации: Journal Article
Дата публикации: 2021-05-27
scimago Q1
wos Q1
БС1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
34042435
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
A method for obtaining perchlorinated di-S,S-substituted derivatives of the closo-decaborate anion with various alkyl groups has been developed: [B10Cl9SR2]- (R= i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, n-C18H37, CH2Ph, and cyclo-S(CH2)4). The method is based on the preparation of the sulfonium-substituted anion [B10H9SR2]- by alkylation of the anion [B10H9SH]2- with bromoalkanes (i-C3H7Br, n-C3H7Br, n-C4H9Br, n-C8H17Br, n-C12H25Br, n-C18H37Br, PhCH2Br, and BrCH2(CH2)2CH2Br) followed by the cluster chlorination with sulfuryl chloride SO2Cl2 in acetonitrile. The process proceeds until the hydrogen atoms in the boron cluster are completely replaced with chlorine and completes within 60 h. It has been found that the melting point of salts ((C4H9)4N)[B10Cl9SR2] (R= i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, and n-C18H37) strongly depends on the length of the hydrocarbon chain of the substituent R.
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Golubev A. E. et al. Synthesis of Perchlorinated Sulfonium Derivatives of closo-Decaborate Anion [2-B10Cl9SR2]- (R = i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, n-C18H37, CH2Ph, and cyclo-S(CH2)4). // Inorganic Chemistry. 2021. Vol. 60. No. 12. pp. 8592-8604.
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Golubev A. E., Kubasov A. S., Bykov A. Yu., Novikov A. S., Kravchenko E. A., Gippius A. A., Zhurenko S. V., Semenova V. A., Korlyukov A., Grigoriev M. S. Synthesis of Perchlorinated Sulfonium Derivatives of closo-Decaborate Anion [2-B10Cl9SR2]- (R = i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, n-C18H37, CH2Ph, and cyclo-S(CH2)4). // Inorganic Chemistry. 2021. Vol. 60. No. 12. pp. 8592-8604.
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TY - JOUR
DO - 10.1021/ACS.INORGCHEM.1C00516
UR - https://doi.org/10.1021/ACS.INORGCHEM.1C00516
TI - Synthesis of Perchlorinated Sulfonium Derivatives of closo-Decaborate Anion [2-B10Cl9SR2]- (R = i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, n-C18H37, CH2Ph, and cyclo-S(CH2)4).
T2 - Inorganic Chemistry
AU - Golubev, Aleksei E.
AU - Kubasov, Alexey S.
AU - Bykov, Alexander Yu
AU - Novikov, Alexander S.
AU - Kravchenko, Eleonora A
AU - Gippius, Andrei A
AU - Zhurenko, Sergey V
AU - Semenova, Veronica A
AU - Korlyukov, Alexander
AU - Grigoriev, Mikhail S.
PY - 2021
DA - 2021/05/27
PB - American Chemical Society (ACS)
SP - 8592-8604
IS - 12
VL - 60
PMID - 34042435
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2021_Golubev,
author = {Aleksei E. Golubev and Alexey S. Kubasov and Alexander Yu Bykov and Alexander S. Novikov and Eleonora A Kravchenko and Andrei A Gippius and Sergey V Zhurenko and Veronica A Semenova and Alexander Korlyukov and Mikhail S. Grigoriev},
title = {Synthesis of Perchlorinated Sulfonium Derivatives of closo-Decaborate Anion [2-B10Cl9SR2]- (R = i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, n-C18H37, CH2Ph, and cyclo-S(CH2)4).},
journal = {Inorganic Chemistry},
year = {2021},
volume = {60},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/ACS.INORGCHEM.1C00516},
number = {12},
pages = {8592--8604},
doi = {10.1021/ACS.INORGCHEM.1C00516}
}
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Golubev, Aleksei E., et al. “Synthesis of Perchlorinated Sulfonium Derivatives of closo-Decaborate Anion [2-B10Cl9SR2]- (R = i-C3H7, n-C3H7, n-C4H9, n-C8H17, n-C12H25, n-C18H37, CH2Ph, and cyclo-S(CH2)4)..” Inorganic Chemistry, vol. 60, no. 12, May. 2021, pp. 8592-8604. https://doi.org/10.1021/ACS.INORGCHEM.1C00516.