Peroxosolvates: Formation criteria, H2O2 hydrogen bonding, and isomorphism with the corresponding hydrates
Ivan Chernyshov
1, 2
,
Ivan Yu Chernyshov
3, 4
,
Mikhail V. Vener
1, 2, 3, 4
,
Alexander G. Medvedev
1, 3, 5, 6
,
Ovadia Lev
5, 6
,
Publication type: Journal Article
Publication date: 2016-12-02
scimago Q2
wos Q1
SJR: 0.633
CiteScore: 5.6
Impact factor: 3.4
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The Cambridge Structural Database has been used to investigate the detailed environment of H2O2 molecules and hydrogen-bond patterns within “true” peroxosolvates in which the H2O2 molecules do not interact directly with the metal atoms. A study of 65 crystal structures and over 260 hydrogen bonds reveals that H2O2 always forms two H-bonds as proton donors and up to four H-bonds as a proton acceptor, but the latter can be absent altogether. The necessary features of peroxosolvate coformers are clarified. (1) Coformers should not participate in redox reactions with H2O2 and should not catalyze its decomposition. (2) Coformers should be Bronsted bases or exhibit amphoteric properties. The efficiency of the proposed criteria for peroxosolvate formation is illustrated by the synthesis and characterization of several new crystals. Conditions preventing the H2O2/H2O isomorphous substitution are essential for peroxosolvate stability: (1) Every H2O2 in the peroxosolvate has to participate in five or six hydrogen b...
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
2
4
6
8
10
|
|
|
CrystEngComm
10 publications, 14.29%
|
|
|
Crystal Growth and Design
7 publications, 10%
|
|
|
Mendeleev Communications
4 publications, 5.71%
|
|
|
Molecules
3 publications, 4.29%
|
|
|
Acta Crystallographica Section E: Crystallographic Communications
3 publications, 4.29%
|
|
|
Physical Chemistry Chemical Physics
3 publications, 4.29%
|
|
|
Structural Chemistry
3 publications, 4.29%
|
|
|
Angewandte Chemie - International Edition
2 publications, 2.86%
|
|
|
Russian Journal of Inorganic Chemistry
2 publications, 2.86%
|
|
|
Russian Chemical Bulletin
2 publications, 2.86%
|
|
|
Crystals
2 publications, 2.86%
|
|
|
Angewandte Chemie
2 publications, 2.86%
|
|
|
Dalton Transactions
1 publication, 1.43%
|
|
|
Journal of Sol-Gel Science and Technology
1 publication, 1.43%
|
|
|
International Journal of Quantum Chemistry
1 publication, 1.43%
|
|
|
Advanced Materials Interfaces
1 publication, 1.43%
|
|
|
Journal of Colloid and Interface Science
1 publication, 1.43%
|
|
|
ACS Omega
1 publication, 1.43%
|
|
|
Journal of Alloys and Compounds
1 publication, 1.43%
|
|
|
Separation and Purification Technology
1 publication, 1.43%
|
|
|
Computational and Theoretical Chemistry
1 publication, 1.43%
|
|
|
Coordination Chemistry Reviews
1 publication, 1.43%
|
|
|
Journal of Catalysis
1 publication, 1.43%
|
|
|
ChemistrySelect
1 publication, 1.43%
|
|
|
ChemPhysChem
1 publication, 1.43%
|
|
|
Chemosensors
1 publication, 1.43%
|
|
|
Industrial & Engineering Chemistry Research
1 publication, 1.43%
|
|
|
Journal of Physical Chemistry B
1 publication, 1.43%
|
|
|
Green Chemistry
1 publication, 1.43%
|
|
|
Chemical Communications
1 publication, 1.43%
|
|
|
2
4
6
8
10
|
Publishers
|
2
4
6
8
10
12
14
16
|
|
|
Royal Society of Chemistry (RSC)
16 publications, 22.86%
|
|
|
American Chemical Society (ACS)
13 publications, 18.57%
|
|
|
Wiley
9 publications, 12.86%
|
|
|
Springer Nature
7 publications, 10%
|
|
|
MDPI
6 publications, 8.57%
|
|
|
Elsevier
6 publications, 8.57%
|
|
|
Pleiades Publishing
4 publications, 5.71%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
4 publications, 5.71%
|
|
|
International Union of Crystallography (IUCr)
3 publications, 4.29%
|
|
|
Taylor & Francis
1 publication, 1.43%
|
|
|
Walter de Gruyter
1 publication, 1.43%
|
|
|
2
4
6
8
10
12
14
16
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
70
Total citations:
70
Citations from 2024:
19
(27%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Chernyshov I. Yu. et al. Peroxosolvates: Formation criteria, H2O2 hydrogen bonding, and isomorphism with the corresponding hydrates // Crystal Growth and Design. 2016. Vol. 17. No. 1. pp. 214-220.
GOST all authors (up to 50)
Copy
Chernyshov I., Chernyshov I. Yu., Vener M. V., Prikhodchenko P. V., Medvedev A. G., Lev O., Churakov A. V. Peroxosolvates: Formation criteria, H2O2 hydrogen bonding, and isomorphism with the corresponding hydrates // Crystal Growth and Design. 2016. Vol. 17. No. 1. pp. 214-220.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.cgd.6b01449
UR - https://pubs.acs.org/doi/10.1021/acs.cgd.6b01449
TI - Peroxosolvates: Formation criteria, H2O2 hydrogen bonding, and isomorphism with the corresponding hydrates
T2 - Crystal Growth and Design
AU - Chernyshov, Ivan
AU - Chernyshov, Ivan Yu
AU - Vener, Mikhail V.
AU - Prikhodchenko, Petr V.
AU - Medvedev, Alexander G.
AU - Lev, Ovadia
AU - Churakov, Andrei V.
PY - 2016
DA - 2016/12/02
PB - American Chemical Society (ACS)
SP - 214-220
IS - 1
VL - 17
SN - 1528-7483
SN - 1528-7505
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Chernyshov,
author = {Ivan Chernyshov and Ivan Yu Chernyshov and Mikhail V. Vener and Petr V. Prikhodchenko and Alexander G. Medvedev and Ovadia Lev and Andrei V. Churakov},
title = {Peroxosolvates: Formation criteria, H2O2 hydrogen bonding, and isomorphism with the corresponding hydrates},
journal = {Crystal Growth and Design},
year = {2016},
volume = {17},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://pubs.acs.org/doi/10.1021/acs.cgd.6b01449},
number = {1},
pages = {214--220},
doi = {10.1021/acs.cgd.6b01449}
}
Cite this
MLA
Copy
Chernyshov, Ivan Yu., et al. “Peroxosolvates: Formation criteria, H2O2 hydrogen bonding, and isomorphism with the corresponding hydrates.” Crystal Growth and Design, vol. 17, no. 1, Dec. 2016, pp. 214-220. https://pubs.acs.org/doi/10.1021/acs.cgd.6b01449.