Lanthanide Complexes with 2-(Tosylamino)-benzylidene-N-(aryloyl)hydrazones: Universal Luminescent Materials
Тип публикации: Journal Article
Дата публикации: 2019-01-04
scimago Q1
wos Q1
БС1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Краткое описание
Lanthanide complexes Ln(L1)(HL1) (Ln = Lu, Yb, Er, Gd, Eu, Sm) and Ln(L2)(HL2) (Ln = Lu, Yb, Gd, Eu) with 2-(tosylamino)-benzylidene-N-(aryloyl)hydrazones (H2L1, aryloyl = 2-hydroxybenzoyl; H2L2, aryloyl = isonicotinoyl) were obtained with the aim to explore them as new luminescent materials. They were found to form monomeric species independently on the aryloyl group, and their crystal structures were determined from single-crystal X-ray data (Yb(L2)(HL2)·0.5(C2H5OH)), as well as from powder X-ray data by Rietveld refinement (Eu(L1)(HL1)). Ytterbium complexes exhibited intense luminescence, which allowed using them in host-free organic light-emitting diodes, which demonstrated remarkable efficiency of near infrared electroluminescence (50 μW/W) at low voltage (5 V). The special mechanism of europium luminescence quenching allowed using europium complexes as luminescent thermometers, which demonstrated very high sensitivity up to 12%/K. The theory of luminescence thermometry based on a three-level system ...
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Kovalenko A. et al. Lanthanide Complexes with 2-(Tosylamino)-benzylidene-N-(aryloyl)hydrazones: Universal Luminescent Materials // Chemistry of Materials. 2019. Vol. 31. No. 3. pp. 759-773.
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Kovalenko A., Rublev P. O., Tcelykh L., Goloveshkin A. S., Lepnev L. S., Burlov A., Vashchenko A. A., Marciniak L., Magerramov A. M., Shikhaliyev N. G., Vatsadze S. Z., Utochnikova V. Lanthanide Complexes with 2-(Tosylamino)-benzylidene-N-(aryloyl)hydrazones: Universal Luminescent Materials // Chemistry of Materials. 2019. Vol. 31. No. 3. pp. 759-773.
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TY - JOUR
DO - 10.1021/acs.chemmater.8b03675
UR - https://doi.org/10.1021/acs.chemmater.8b03675
TI - Lanthanide Complexes with 2-(Tosylamino)-benzylidene-N-(aryloyl)hydrazones: Universal Luminescent Materials
T2 - Chemistry of Materials
AU - Kovalenko, Anton
AU - Rublev, Pavel O
AU - Tcelykh, L
AU - Goloveshkin, Alexander S.
AU - Lepnev, Leonid S.
AU - Burlov, A.S
AU - Vashchenko, A A
AU - Marciniak, Lukasz
AU - Magerramov, Abel M
AU - Shikhaliyev, Namig G.
AU - Vatsadze, S Zh
AU - Utochnikova, Valentina
PY - 2019
DA - 2019/01/04
PB - American Chemical Society (ACS)
SP - 759-773
IS - 3
VL - 31
SN - 0897-4756
SN - 1520-5002
ER -
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@article{2019_Kovalenko,
author = {Anton Kovalenko and Pavel O Rublev and L Tcelykh and Alexander S. Goloveshkin and Leonid S. Lepnev and A.S Burlov and A A Vashchenko and Lukasz Marciniak and Abel M Magerramov and Namig G. Shikhaliyev and S Zh Vatsadze and Valentina Utochnikova},
title = {Lanthanide Complexes with 2-(Tosylamino)-benzylidene-N-(aryloyl)hydrazones: Universal Luminescent Materials},
journal = {Chemistry of Materials},
year = {2019},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acs.chemmater.8b03675},
number = {3},
pages = {759--773},
doi = {10.1021/acs.chemmater.8b03675}
}
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MLA
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Kovalenko, Anton, et al. “Lanthanide Complexes with 2-(Tosylamino)-benzylidene-N-(aryloyl)hydrazones: Universal Luminescent Materials.” Chemistry of Materials, vol. 31, no. 3, Jan. 2019, pp. 759-773. https://doi.org/10.1021/acs.chemmater.8b03675.